Calorimetry Group Proposal v2.2
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1
Chemical ThinkingCalorimetry
Group Proposal
v2.2
|
Calorimetry
Group Proposal
Your name:
Your email:
Your lab partner’s name(s):
Your lab partner’s email(s):
Your lab instructor’s name:
Your lab section:
1.
Overall Goals (1 pt)
. In complete, well-written sentences, summarize in your own words the
overall goals
for the
Calorimetry
Project
.
the overall goals of this lab is determining the strike geometry and reaction enthalpy of the unknown compound
(1.0 M compound A) with the 1.0 M NaOH
2.
Compound A/NaOH Exploration Results (4 pts)
. Follow the plan detailed in the
Method of Variation Step-Up Infographic
and the
Stoichiometry by the Method of Variation Infographic
. Notice, you are working with another group.
Group 1
will
prepare and run the first subset of six (6) Compound A/NaOH volume combinations, while
Group 2
concurrently prepares and
runs the second subset of six (6) to efficiently build a complete data set. Clearly record in
Table 1.1
Group 1’s
temperature
values. Likewise, document in
Table 1.2
Group 2’s
temperature results.
Table 1.1.
GROUP 1
Compound A + Sodium Hydroxide Volume Combination Temperature Results
A
B
C
D
E
F
1.0 M
Compound A
Volume (mL)
1.00
2.00
2.50
3.00
3.50
4.00
1.0 M
Sodium Hydroxide
Volume (mL)
9.00
8.00
7.50
7.00
6.50
6.00
Total Volume (mL)
10.00
10.00
10.00
10.00
10.00
10.00
Initial Temperature, T
i
(
o
C)
18.60
18.70
18.90
18.70
18.90
18.80
Final Temperature, T
f
(
o
C)
19.50
20.60
21.50
21.60
22.50
22.90
Temperature change,
T (
o
C)
∆
0.9
1.9
2.6
2.9
3.6
4.1
Table 1.2.
GROUP 2
Compound A + Sodium Hydroxide Volume Combination Temperature Results
G
H
I
J
K
L
1.0 M
Compound A
Volume (mL)
4.50
5.00
6.00
7.00
8.00
9.00
1.0 M
Sodium Hydroxide
Volume (mL)
5.50
5.00
4.00
3.00
2.00
1.00
Total Volume (mL)
10.00
10.00
10.00
10.00
10.00
10.00
Initial Temperature, T
i
(
o
C)
18.1
17.2
16.9
16.9
17
16.6
Final Temperature, T
f
(
o
C)
22.7
22.1
20.6
19.6
18.6
17.5
CHEM 152 CP
v2.2
07-08-23
2
Chemical ThinkingCalorimetry
Group Proposal
v2.2
|
Temperature change,
T (
o
C)
∆
4.6
4.9
3.7
2.7
1.6
0.9
CHEM 152 CP
v2.2
07-08-23
3
Chemical ThinkingCalorimetry
Group Proposal
v2.2
|
nmn
3.
Compound A/NaOH
Δ
T vs. Solution Volume Graph (4 pts)
. Plot the combined
Table 1.1
and
Table 1.2
experimental data
accordant with the
Stoichiometry by the Method of Variation Infographic
and
Calorimetry Project Guide
. Paste-in the
complete graph below
.
CHEM 152 CP
v2.2
07-08-23
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4
Chemical ThinkingCalorimetry
Group Proposal
v2.2
|
CHEM 152 CP
v2.2
07-08-23
5
Chemical ThinkingCalorimetry
Group Proposal
v2.2
|
Analyze the above graph and determine the
stoichiometry
between Compound A and NaOH. Unambiguously state (by filling in
the “blanks”) the
stoichiometry
results
:
1 Compound A
(aq)
+1 NaOH
(aq)
→
Products
(aq)
4.
Calorimeter Calibration Constant
.
(2 pts)
.
5.
Compound A/NaOH Reaction Enthalpy (4 pts)
.
CHEM 152 CP
v2.2
07-08-23
6
Chemical ThinkingCalorimetry
Group Proposal
v2.2
|
CHEM 152 CP
v2.2
07-08-23
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Chemical ThinkingCalorimetry
Group Proposal
v2.2
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6.
Group Proposal (Outline) (5 pts)
.
1)
We were group 2, so we got 12 vials and we filled each vial with the amounts of NaoH and compound A
given
2)
Then we make sure that out amounts are correct by putting poring ea8ch vial individually in the graduated
cylinder and make sure the amounts are correct
3)
Put the temperature probe in the G2 vial, and measure the temperature with only compound A.
4)
Measure the temperature with mixed compound A and NaOH together.
5)
COllect the date and calculate the
Calorimeter Calibration Constant and compound A/NaOH Reaction Enthalpy.
6)
Make an excel graph showing the peak and stoichiometric values.
7)
Use the equation (rxn=q(soln) and deltaH(rxn)/mol(unknown)
8)
for4 the4 calibration constant, we got it by dividing the Gof the surrounding (given) my our q which was ( S of the
surrounding (given), density of the solution which is given and then v total which is 10 and the delta Temperature of
the NaOH and Hcl
9)
for the delta H, we got it by diving the q of the reaction by mol y
CHEM 152 CP
v2.2
07-08-23
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Date
Name
Section
galauvinstenos
Pre-Laboratory Assignment
1. Read an authoritative source for a discussion of preparing and interpreting a graph, especially the
extrapolation of a curve.
2. A student determined the calorimeter constant of the calorimeter, using the procedure described in
this module. The student added 50.00 mL of cold water to 50.00 mL of heated, distilled water in a
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The maximum temperature of the mixture was found to be 24.81 °C. Assume the density of water is
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gniwollot bns of toh bine
botollon ot ssb om
(1) Determine the AT for the hot water and the cold water.
mit
At cold water = 24.8I- 21,00 = 3.81°COn
आनी
AT hot = 24.81- 29.15 =
- 4.34°C
60.ES
2.0
0LES
8.
0.1
0.0
If
0.8
28.5S
Calculate N
0.4
08.TT
gabxim
02
4.34°C
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81
answer
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dogesn boximnu sdt to anuiSTeqmad mom…
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Row 3: Your answer is wrong. In addition to checking your math, check that you used the right data and DID NOT round any intermediate calculations.
A student runs two experiments with a constant-volume "bomb" calorimeter containing 1100. g of water (see sketch at
right).
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oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed
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ORT SHEET
Heat of Neutralization
EXPERIMENT
elemsboomfchg lom
12
A. Heat Capacity of Calorimeter
1. Temp. of calorimeter and water before mixing
2. Temp. of warm water
°C
22.0
39,0
30.3
3. Maximum temp. determined from your curve
°C
4. Heat lost by warm water (temp decrease x
°C
50.0 g x 4.184 J/K-g) =
02),
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50.0 g x 4.184 J/K-g) =
30,3 22.0)x
13626J
s0.0gmpi
S0.0gy
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7. Heat capacity of calorimeter:
heat gained by the calorimeter
temperature increase
J/K
3. Heat of Neutralization of HCl-NaOH
22.2
22.2.
°C
. Temp. of calorimeter and NaOH
Temp. of HCI
AT determined from your curve after adding HC1
°C
to the NaOH
Heat gained by solution (temperature increase x ON
100 g x 4.184 J/K-g) =
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%3D
Heat gained by calorimeter (temperature increase x
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%3D
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Tight O 2018 Pearson Education, Inc.
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22
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thermometer
A 52.3 g sample of quartz is put into a calorimeter (see sketch at right) that contains 100.0 g of water. The quartz sample starts off
alo
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Calculate the specific heat capacity of quartz according to this experiment. Be sure your answer is rounded to 2 significant digits.
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Problem 12.50
Part A
Zinc sulfide, ZnS, crystallizes in a face-centered cubic unit cell where
the cations occupy one of the two types of tetrahedral holes.
How many Zn²+ ions touch each S2-ion?
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ΨΕ ΑΣΦ
S
Zn
>
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Request Answer
Part B
How many S2 ions touch each Zn²+ ion?
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