chem1c-worksheet-kinetics-answer-key

pdf

School

Dunman High School *

*We aren’t endorsed by this school

Course

9744

Subject

Chemistry

Date

Nov 24, 2024

Type

pdf

Pages

5

Uploaded by jsby0210

Report
Studocu is not sponsored or endorsed by any college or university Chem1C Worksheet Kinetics answer key General Chemistry (University of California Irvine) Studocu is not sponsored or endorsed by any college or university Chem1C Worksheet Kinetics answer key General Chemistry (University of California Irvine) Downloaded by Timothy Handoko (hantimo210@gmail.com) lOMoARcPSD|23633319
1 Chem 1C General Chemistry Joe Patterson Worksheet 1 Week of April 8, 2019 1. Consider the reaction, NOCl (g) NO + ½ Cl 2 (g), with initial concentration of NOCl= 0.5 M. a. Show how [NOCl], [NO], and [Cl 2 ] change with time by sketching a plot of concentration with time. Draw a plot that shows [NOCl] decreasing over time and NO and ½ Cl 2 increasing. b. Write an expression for the rate of disappearance of NOCl and for the rate of appearance of NO and Cl 2 , showing how these are related to each other Rate = ?[????] ?? = ?[??] ?? = 2 ?[?? 2 ] ?? c. The following data for the disappearance of NOCl was observed in an experiment: [NOCl] 0 (M) Initial Rate (mol L -1 s -1 ) 0.25 8.0 x 10 -5 0.50 3.2 x 10 -4 1.00 1.3 x 10 -3 Second order rxn d. Calculate the rate constant. 0.00128 M -1 s -1 e. Calculate the half-life for the decomposition of NOCl when the concentration of NOCl is 0.5 M. 1562.5 per second Downloaded by Timothy Handoko (hantimo210@gmail.com) lOMoARcPSD|23633319
2 f. For the reaction in part (e), calculate [NOCl] after 2 hours has passed. 0.089 M Reasoning: ? = 1 ? 1/2 [? 0 ] plug this equation into: 1 [?] = 1 ? 0 + ?? So: 1 [?] = 1 0.5 + (0.00128)(7200) = 0.089 M The other way told to solve it in discussion (0.5 x (1/2)^4.6) is only valid for linear/0 order problems not for first and second order reactions, which grow exponentially . 2. Given the following rate law: Rate = k[NO] 2 [H 2 ] a. Write the reaction order with respect to each reactant [ NO] 2 occurs in second order [H 2 ] occurs in first order b. Write the overall reaction rate Third order c. If the concentration of NO is cut in half, identify what happens to the reaction rate. (1/2) 2 = ¼ as fast d. If the concentration of NO is quadrupled, identify what happens to the reaction rate. (4) 2 = 16 as fast 3. The kinetics of the reaction that depletes the ozone layer in the atmosphere was studied by performing two experiments. In experiment A, the rate of disappearance of NO was followed in the presence of a large excess of O 3 (1.0 x 10 3 M). In Experiment B, the rate of disappearance of O 3 was followed in the presence of a large excess of NO (2.0 x 10 3 M). The data for these two experiments are plotted in several different formats. (Concentrations are in units of M and time is in seconds). NO (g) + O 3 (g) NO 2 (g) + O 2 (g) Downloaded by Timothy Handoko (hantimo210@gmail.com) lOMoARcPSD|23633319
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help
3 a. Write the reaction order in respect to each reactant. Both NO and O 3 are first order b. Write the overall rate order. Second c. Provide the value of the rates for each set of experiments. Experiment A when: [NO]k=Rate Experiment B when: [O 3 ]k = Rate [NO] 0 (M) Rate [O 3 ] 0 (M) Rate (mol L -1 s -1 ) 6 0.0108 10 0.036 3 0.0054 5 0.018 1 0.0018 1 0.0036 Downloaded by Timothy Handoko (hantimo210@gmail.com) lOMoARcPSD|23633319
4 Downloaded by Timothy Handoko (hantimo210@gmail.com) lOMoARcPSD|23633319