CHEM 102 - Recitation Week10
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CHEM 102 Recitation Week 10
Using the
"Key Concepts"
and the
"Key Equations and Relationships"
in the Chapter
Summary
at the end of each chapter, identify and type in this Word document some concepts
and/or equations
needed to solve each item. Be prepared to share your ideas in class
discussions. You are not required to solve the problems in details. If you choose to do it, do not
forget to also identify the concepts to get full credit (see posted Answer Keys
for previous
weeks).
Ch. 21, 33 Based on the molecular formula, determine whether each compound is an alkane, alkene or alkyne. (Assume that the hydrocarbons are noncyclic and there is no more than one multiple bond.)
CONCEPT: differentiation of hydrocarbons, counting numbers of bonds
a.
C
5
H
12
b.
C
3
H
6
c.
C
7
H
12
d.
C
11
H
22
Ch. 21, 35 Write structural formulas for each of the nine structural isomers of heptane.
CONCEPT: definitions of isomer and heptane
Ch. 21, 42 Name each alkane.
CONCEPT: definition of alkane, defining structure through length and number of bonds
a.
b.
c.
d.
Ch. 21, 44 Draw a structure for each alkane.
CONCEPT: identifying length/number of bonds through the number, prefix, and suffixes
b.
3-isopropylheptane
c.
4-ethyl-2,2-dimethylhexane
Ch. 21, 50
Write structural formulas for each of the possible isomers of n
-pentyne that are formed by moving the position of the triple bond.
CONCEPT: all have same molecular formula but different connections, where can the triple bonds move
Ch. 21, 51 Name each alkene.
CONCEPT: identified by longest chain containing double bond
1
a.
d.
Ch. 21, 54 Name each alkyne.
CONCEPT: identified by longest chain containing triple bond
c.
d.
Ch. 21, 55 Draw the correct structure for each compound.
CONCEPT: use numbers, prefixes, and suffixes to identify how many carbons and hydrogens (triple bond on which carbon)
a.
4-octyne
d.
5-ethyl-3,6-dimethyl-2-heptene
Ch. 21, 68 Draw the structure for each compound.
CONCEPT: use numbers, prefixes, and suffixes to determine how many carbons and hydrogens (double bond on which carbon)
a.
ethylbenzene
b.
1-iodo-2-methylbenzene
c. para
-diethylbenzene
Ch. 21, 72 Draw the structure for each alcohol. CONCEPT: all in alkyl group, classified on which carbon is bonded to hydroxyl, bond angles about 109 degrees
a)
2-butanol
d)
2-methyl-3-pentanol
Ch. 21, 79 Name each carboxylic acid or ester CONCEPT: difference between carboxylic acid and ester, count bonds and placements
2
Ch. 21, 94 Determine whether each pair of structures are isomers or the same molecule drawn two different ways. CONCEPT: same molecule if it can be rotated or name can be written the same way
Ch. 12, 69 Teflon is an addition polymer formed from the monomer shown here. Draw the structure of the polymer. CONCEPT: definition of addition polymer, single c-c bond when more carbons are added Ch. 12, 72 Nomex, a condensation copolymer used by firefighters because of its flame-resistant properties, forms from isophthalic acid and m
-aminoaniline. Draw the structure of the dimer and of the polymer.
(
Hint
:
Water is eliminated when the bond between the monomers forms.) CONCEPT: definitions of isophthalic acid and m
-aminoaniline, definition of dimer in a polymer
Isophthalic acid:
m-Aminoaniline
:
3
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:
Ch. 21, 46a Complete and balance each hydrocarbon combustion reaction.
CONCEPT: writing combustion equations, same number of each atom on both sides of reaction
CH
3
-CH
2
-CH
3
+ O
2
→
Ch. 21, 96 How many kilograms of CO
2
does the complete combustion of 3.8 kg of n
-octane produce?
CONCEPT: ratio of atoms in a combustion reaction, chemical expression of n
-octane and number of moles in 3.8 kg
4
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