120L Ex2 Identification of a solid acid report sheets - CHEM 120L - Spring 2022
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University of Waterloo *
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120L
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Chemistry
Date
May 24, 2024
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4
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Experiment 2: Identification of an Unknown Solid Acid Post-lab Report Sheets Name: Student ID #: Submission date: TA: Partner: Experimental objectives: * To gain experience in the techniques of weighing by difference, quantitative transfer and standardization titrations * To prepare a primary standard solution, use this solution to determine the concentration of a sodium hydroxide standard * To use an NaOH standard to titrate against an unknown solid acid in order to determine the molar mass and thus identity of the unknown from the set of possible unknowns * To develop skill in the use of unit analysis for calculations Results Part A: NOTE: Marks are deducted each time 1-2 line unit analysis is not used AND each time significant figures are incorrect. Use care in all calculations! Mass of oxalic acid used: Sample calculation for determining the concentration of oxalic acid, using unit analysis: Concentration of oxalic acid:
Sample calculation for determining the concentration of NaOH, using unit analysis: Titration Volume of oxalic acid Volume of NaOH Concentration of NaOH # (mL) (mL) ™) 1 2 3 Average Concentration of NaOH from Part A: Results Part B: Unknown #: Titration # Mass of Unknown (8) Volume of NaOH (mL)
Sample calculation of unknown molar mass assuming the acid is monoprotic, using unit analysis: Sample calculation of unknown molar mass assuming the acid is diprotic, using unit analysis: Sample calculation of unknown molar mass assuming the acid is triprotic, using unit analysis: Sample calculation for determination of the average molar mass:
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Molar Mass Sample Monoprotic Diprotic Triprotic 3 Average Molar Mass: Conclusion: Write a formal lab report conclusion for this experiment and attach it as the next page in these report sheets. Refer to LEARN - Content - Lab reports for information on writing formal lab report conclusions. Maximum length for this conclusion is one page, double spaced. Be sure to summarize the results from all the experimental objectives outlined in this report and include both the identity and # of your unknown. References: If you use any resources in preparing this report, you must provide reference information for them here: Attachments to your report: * Your experimental procedure summary will be graded as part of your lab report. Attach it behind the report sheets. * Your Data Sheet must be submitted with your report as proof that you performed the experiment, attach it as the last page of your report.
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Given the following information complete the last (blank) data table
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00 mL of a diprotic acid primary standard solution was accurately prepared to a concentration of 0.1431 M. Three samples of this primary standard solution were used as samples in a titration to standardize an aqueous solution of sodium hydroxide, NaOH, which would be used as a titrant.
Using the following table of data for the titration of the primary standard acid with NaOH, calculate the average concentration of NaOH.
Trial #
Volume of primary standard
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Final titrant volume
1
10.00 mL
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10.00 mL
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46.23 mL
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0.1506 M
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Standardization of 0.1 M NAOH
Trial 1
Mass KHP used, g
0.297 g
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Concentration sodium thiosulfate solution used:
0.056 mol L-1
ACCURATE TITRATION VOLUME OF SODIUM THIOSULFATE SOLUTION USED
Volume titration 1, (ml)
Volume titration 2, (ml)
Your Group
15.80
15.75
Group 1
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15.70
Group 2
16.30
16.25
ANALYSIS
Average volume used, (mL)
Standard deviation
Number of moles sodium thiosulfate used, (mol)
Number of moles calcium iodate in solution, (mol)
Volume of calcium iodate used, (mL)
Concentration of saturated calcium iodate solution (mol L-¹)
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0.26220
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Concentration sodium thiosulfate solution used:
0.056 mol L-1
ACCURATE TITRATION VOLUME OF SODIUM THIOSULFATE SOLUTION USED
Volume titration 1, (mL)
Volume titration 2, (mL)
Your Group
15.80
15.75
Group 1
16.05
15.70
Group 2
16.30
16.25
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Standard deviation
Number of moles sodium thiosulfate used, (mol)
Number of moles calcium iodate in solution, (mol)
Volume of calcium iodate used, (mL)
Concentration of saturated calcium iodate solution (mol L-¹)
Unrounded value
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Table 12.9 (data)
Buffer
Initial pH
pH after adding HCI pH after adding NaOH
6
8
6
4
Solution A 5-6
8
Solution B8-9
10
Solution C7
9-10
Solution D 5
Boiled distilled water 5
9-10
4
9
Table 12.10 (report)
Solutions able to buffer well against acid
Solutions able to buffer well against base
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Table 2. Titration data
Trial 1
Trial 2
Trial 3
Initial burette reading (mL)
1.19
2.26
2.39
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0.100
0.100
0.100
Volume of vinegar sample (mL)
5.00
5.00
5.00
Final burette reading (mL)
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49.43
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Average Volume of NaOH used in liters
Average moles of NaOH used (mol)
Average moles of acetic acid (mol)
Average molarity of acetic acid (M)
Average mass of acetic acid (g)
Average mass of vinegar (g) (assume the density of vinegar is 1.00 g/mL)
Average mass % of acetic acid in vinegar
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Percent Error
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Part II: Titration of Vinegar with
Standaralzed Naun
Report Table AV.4: Part 2 Calculations.
Data and Calculations for three trials
Part II: Titration of Vinegar with Standardized auη
Report Table AV.4: Part 2 Calculations
Data and Calculations for three trials
Table view
List view
Trial 1
Trial 2
Trial 3
Volume of Vinegar Titrated (mL)
10.00
10.00
10.00
Initial Buret Reading (mL)
4.00
13.20
23.10
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13.20
23.10
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Mass Acetic Acid (g)
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Table 12.5 (data)
Indicator
Color in 0.05 M HCl
Color in 0.05 M NaOH
Methyl red
Bromcresol
Phenolphthalein
Methyl orange
Methyl violet
Table 12.6 (report)
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