Part A The rate constant for a certain reaction is = 8.40x10 s. If the initial reactant concentration was 0.700 M, what will the concentration be after 4.00 minutes? Express your answer with the appropriate units. ▸ View Available Hint(s) (A) = Templates Symboly undo reso Teset keyboard shortcuts Help Value Units Submit Previous Answere X Incorrect: Try Again; 4 attempts remaining Part B Azero-order reaction has a constant rate of 2.30×10 M/s. If after 65.0 seconds the concentration has dropped to 4.00×102 M, what was the initial concentration? Express your answer with the appropriate units. ▸ View Available Hint(s) Tempjeres Symbols undo' rego es keyboard shortcuts Help Units (A) = Value
Part A The rate constant for a certain reaction is = 8.40x10 s. If the initial reactant concentration was 0.700 M, what will the concentration be after 4.00 minutes? Express your answer with the appropriate units. ▸ View Available Hint(s) (A) = Templates Symboly undo reso Teset keyboard shortcuts Help Value Units Submit Previous Answere X Incorrect: Try Again; 4 attempts remaining Part B Azero-order reaction has a constant rate of 2.30×10 M/s. If after 65.0 seconds the concentration has dropped to 4.00×102 M, what was the initial concentration? Express your answer with the appropriate units. ▸ View Available Hint(s) Tempjeres Symbols undo' rego es keyboard shortcuts Help Units (A) = Value
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![Introduction to Integrated Rate Laws
Learning Goal:
To understand how to use integrated rate laws to solve for concentration.
A car starts at mile marker 145 on a highway and drives at 55 mi/hr in the direction of
decreasing marker numbers. What mile marker will the car reach after 2 hours?
This problem can easily be solved by calculating how far the car travels and
subtracting that distance from the starting marker of 145.
55 mi/hr x 2 hr = 110 miles traveled
milemarker 145 -110 miles milemarker 35
If we were to write a formula for this calculation, we might express it as follows:
milemarkero- (speed x time)
milemarker
where milemarker is the current milemarker and milemarker, is the initial
milemarker.
Similarly, the integrated rate law for a zero-order reaction is expressed as follows:
[A]orate x time
[A]
or
since
rate k[A] = k
Azero-order reaction (Figure 1)proceeds uniformly over time. In other words, the rate
does not change as the reactant concentration changes. In contrast, first-order
reaction rates (Figure 2) do change over time as the reactant concentration changes.
[A] [A]o-kt
Because the rate of a first-order reaction is nonuniform, its integrated rate law is
slightly more complicated than that of a zero-order reaction.
The integrated rate law for a first-order reaction is expressed as follows:
[A] = [A]oekt
where & is the rate constant for this reaction.
Figure
[A]
zero-order
time
< 1 of 2 >
▾ Part A
The rate constant for a certain reaction is k = 6.40x10³ s. If the initial reactant concentration was 0.700 M, what will the concentration be after 4.00 minutes?
Express your answer with the appropriate units.
► View Available Hint(s)
[A] =
Submit
▾ Part B
Templates Symbols undo regio Teset keyboard shortcuts Help
[A]o =
X Incorrect; Try Again; 4 attempts remaining
Submit
Value
Previous Answers
Azero-order reaction has a constant rate of 2.30x10 M/s. If after 65.0 seconds the concentration has dropped to 4.00×102 M, what was the initial concentration?
Express your answer with the appropriate units.
▸ View Available Hint(s)
Provide Feedback
Units
Templates Symbols undo redo Teset keyboard shortcuts Help
n
Units
Value
Review | Con](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F096b6bb3-2f11-49d8-9074-81efda173389%2F3ee69088-1229-4681-8a23-a57bb2a1986e%2Ffyojrym_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Introduction to Integrated Rate Laws
Learning Goal:
To understand how to use integrated rate laws to solve for concentration.
A car starts at mile marker 145 on a highway and drives at 55 mi/hr in the direction of
decreasing marker numbers. What mile marker will the car reach after 2 hours?
This problem can easily be solved by calculating how far the car travels and
subtracting that distance from the starting marker of 145.
55 mi/hr x 2 hr = 110 miles traveled
milemarker 145 -110 miles milemarker 35
If we were to write a formula for this calculation, we might express it as follows:
milemarkero- (speed x time)
milemarker
where milemarker is the current milemarker and milemarker, is the initial
milemarker.
Similarly, the integrated rate law for a zero-order reaction is expressed as follows:
[A]orate x time
[A]
or
since
rate k[A] = k
Azero-order reaction (Figure 1)proceeds uniformly over time. In other words, the rate
does not change as the reactant concentration changes. In contrast, first-order
reaction rates (Figure 2) do change over time as the reactant concentration changes.
[A] [A]o-kt
Because the rate of a first-order reaction is nonuniform, its integrated rate law is
slightly more complicated than that of a zero-order reaction.
The integrated rate law for a first-order reaction is expressed as follows:
[A] = [A]oekt
where & is the rate constant for this reaction.
Figure
[A]
zero-order
time
< 1 of 2 >
▾ Part A
The rate constant for a certain reaction is k = 6.40x10³ s. If the initial reactant concentration was 0.700 M, what will the concentration be after 4.00 minutes?
Express your answer with the appropriate units.
► View Available Hint(s)
[A] =
Submit
▾ Part B
Templates Symbols undo regio Teset keyboard shortcuts Help
[A]o =
X Incorrect; Try Again; 4 attempts remaining
Submit
Value
Previous Answers
Azero-order reaction has a constant rate of 2.30x10 M/s. If after 65.0 seconds the concentration has dropped to 4.00×102 M, what was the initial concentration?
Express your answer with the appropriate units.
▸ View Available Hint(s)
Provide Feedback
Units
Templates Symbols undo redo Teset keyboard shortcuts Help
n
Units
Value
Review | Con
Expert Solution
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Step 1
In this question given Rate constant of a certain reaction is K = 6.40 × 10–3 s–1. If initial reactant concentration was 0.700 M .
We have to calculate the concentration of the reactant after 4 min.
Again, for a zero order reaction reaction given constant rate of the reaction 2.3 × 10–4 M/s . After 65 seconds concentration drops to 4.00 × 10–2 M .
We have to calculate the initial concentration of the reactant.
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