Solutions for Chemistry: A Molecular Approach
Problem 1SAQ:
Q1. According to Coulomb's law, if the separation between two particles of the same charge is...Problem 2SAQ:
Q2. Which electron in sulfur is most shielded from nuclear charge?
a) an electron in the 1s...Problem 8SAQ:
Q8. Which statement is true about effective nuclear charge?
a) Effective nuclear charge decreases...Problem 11SAQ:
Arrange these atoms and ions in order of increasing radius: Cs+,Xe,I. a) IXeCs+ b) Cs+XeI c) XeCs+I...Problem 13SAQ:
Q13. The ionization energies of an unknown third-period element are listed here. Identify the...Problem 14SAQ:
Which statement is true about trends in metallic character? a) Metallic character increases as you...Problem 15SAQ:
Q15. For which element is the gaining of an electron most exothermic?
a) Li
b) N
c) F
d) B
Problem 1E:
1. What are periodic properties?
Problem 4E:
4. Who is credited with arranging the periodic table? How are the elements arranged in the modern...Problem 10E:
10. What is penetration? How does the penetration of an orbital into the region occupied by core...Problem 11E:
11. Why are the sublevels within a principal level split into different energies for multielectron...Problem 12E:
12. What is an orbital diagram? Provide an example.
Problem 21E:
21. Describe the relationship between an element’s row number in the periodic table and the highest...Problem 22E:
22. Which of the transition elements in the first transition series have anomalous electron...Problem 23E:
23. Describe how to write the electron configuration for an element based on its position in the...Problem 33E:
33. What is ionization energy? What is the difference between first ionization energy and second...Problem 34E:
34. What is the general trend in the first ionization energy as you move down a column in the...Problem 35E:
35. What are the exceptions to the periodic trends in the first ionization energy? Why do they...Problem 36E:
36. Examination of the first few successive ionization energies for a given element usually reveals...Problem 39E:
39. Write a general equation for the reaction of an alkali metal with each substance.
a. a...Problem 45E:
45. Use the periodic table to write an electron configuration for each element. Represent core...Problem 46E:
46. Use the periodic table to determine the element corresponding to each electron configuration.
Problem 47E:
47. Use the periodic table to determine each quantity.
a. The number of 2s electrons in Li.
b. The...Problem 48E:
48. Use the periodic table to determine each quantity.
a. The number of 3s electrons in Mg
b. The...Problem 49E:
Name an element in the fourth period (row) of the periodictable with: a. Five valence electrons b....Problem 50E:
50. Name an element in the third period (row) of the periodic table with the following:
a. Three...Problem 51E:
51. Determine the number of valence electrons in an atom of each element.
a. Ba b. Cs c. Ni d. S
Problem 53E:
53. Which outer electron configuration would you expect to belong to a reactive metal? To a reactive...Problem 55E:
55. According to Coulomb’s law, which pair of charged particles has the lowest potential energy?
a....Problem 56E:
56. According to Coulomb’s law, rank the interactions between charged particles from lowest...Problem 57E:
57. Which of the following will experience a greater effective nuclear charge: the valence electrons...Problem 58E:
58. Arrange the atoms according to decreasing effective nuclear charge experienced by their valence...Problem 59E:
59. If core electrons completely shielded valence electrons from nuclear charge (i.e., if each core...Problem 67E:
67. Write orbital diagrams for each ion and indicate whether the ion is diamagnetic or...Problem 73E:
73. Choose the element with the higher first ionization energy from each pair.
a. Br or Bi b. Na or...Problem 77E:
77. For each element, predict where the “jump” occurs for successive ionization energies. (For...Problem 78E:
78. Consider this set of ionization energies.
To which third-period element do these ionization...Problem 79E:
79. Choose the element with the more negative (more exothermic) electron affinity from each pair:
a....Problem 81E:
81. Choose the more metallic element from each pair.
a. Sr or Sb b. As or Bi c. Cl or O d. S or As
Problem 83E:
83. Arrange these elements in order of increasing metallic character: Fr, Sb, In, S, Ba, Se.
Problem 99E:
99. Consider these elements: N, Mg, O, F, and Al.
a. Write the electron configuration for each...Problem 106E:
106. The electron affinity of each group 5A element is more positive than that of each corresponding...Problem 107E:
107. The elements with atomic numbers 35 and 53 have similar chemical properties. Based on their...Problem 112E:
112. The first ionization energy of sodium is 496 kJ/mol. Use Coulomb’s law to estimate the average...Problem 113E:
115. Consider the densities and atomic radii of the noble gases at 25 °C:
Element Atomic Radius...Problem 114E:
116. As you have seen, the periodic table is a result of empirical observation (i.e., the periodic...Problem 115E:
117. Consider the metals in the first transition series. Use periodic trends to predict a trend in...Problem 116E:
118. Imagine a universe in which the value of ms can be +, 0, and –. Assuming that all the other...Problem 121E:
123. Unlike the elements in groups 1A and 2A, those in group 3A do not show a regular decrease in...Problem 122E:
124. Using the data in Figures 8.15 and 8.16, calculate ΔE for the reaction Na(g) + Cl(g) → Na+(g) +...Problem 123E:
125. Even though adding two electrons to O or S forms an ion with a noble gas electron...Problem 125E:
127. The heaviest known alkaline earth metal is radium, atomic number 88. Find the atomic numbers of...Problem 129E:
131. Imagine that in another universe atoms and elements are identical to ours, except that atoms...Problem 130E:
132. The outermost valence electron in atom A experiences an effective nuclear charge of 2+ and is...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding Ii: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - SolutionsChapter 13 - Chemical KineticsChapter 14 - Chemical EquilibriumChapter 15 - Acids And BasesChapter 16 - Aqueous Ionic EquilibriumChapter 17 - Free Energy And ThermodynamicsChapter 18 - ElectrochemistryChapter 19 - Radioactivity And Nuclear ChemistryChapter 20 - Organic ChemistryChapter 21 - BiochemistryChapter 22 - Chemistry Of The NonmentalsChapter 23 - Metals And MetallurgyChapter 24 - Transition Metals And Coordination Compounds
Book Details
Chemistry: A Molecular Approach, Third Edition is an innovative, pedagogically driven text that explains challenging concepts in a student-oriented manner. Nivaldo Tro creates a rigorous and accessible treatment of general chemistry in the context of relevance and the big picture. Chemistry is presented visually through multi-level images - macroscopic, molecular, and symbolic representations - helping students see the connections between the world they see around them (macroscopic), the atoms and molecules that compose the world (molecular), and the formulas they write down on paper (symbolic). The hallmarks of Dr. Tro's problem-solving approach are reinforced through interactive media that provide students with an office-hour type of environment built around worked examples and expanded coverage on the latest developments in chemistry. Pioneering features allow students to sketch their ideas through new problems, and much more.
Sample Solutions for this Textbook
We offer sample solutions for Chemistry: A Molecular Approach homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Explanation: Given info: The amount of the heat produced = 155kJ. The amount of the work done =...Chapter 7, Problem 1SAQChapter 8, Problem 1SAQExplanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Chapter 13, Problem 1SAQJustify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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