Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780321809247
Author: Nivaldo J. Tro
Publisher: Prentice Hall
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Chapter 8, Problem 105E
Interpretation Introduction
To determine: The general outer electron configuration for groups
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81. a. Propose a mechanism for the following reaction:
OH
CH2=CHCHC=N
b. What is the product of the following reaction?
HO
H₂O
N=CCH2CH2CH
OH
HO
CH3CCH=CH2
H₂O
C=N
82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
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G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
فا
Explanation
Check
Click and drag to start drawing a
structure.
Chapter 8 Solutions
Chemistry: A Molecular Approach
Ch. 8 - Q1. According to Coulomb's law, if the separation...Ch. 8 - Q2. Which electron in sulfur is most shielded from...Ch. 8 - Prob. 3SAQCh. 8 - Prob. 4SAQCh. 8 - Prob. 5SAQCh. 8 - Prob. 6SAQCh. 8 - Prob. 7SAQCh. 8 - Q8. Which statement is true about effective...Ch. 8 - Prob. 9SAQCh. 8 - Prob. 10SAQ
Ch. 8 - Arrange these atoms and ions in order of...Ch. 8 - Prob. 12SAQCh. 8 - Q13. The ionization energies of an unknown...Ch. 8 - Which statement is true about trends in metallic...Ch. 8 - Q15. For which element is the gaining of an...Ch. 8 - 1. What are periodic properties?
Ch. 8 - Prob. 2ECh. 8 - Prob. 3ECh. 8 - 4. Who is credited with arranging the periodic...Ch. 8 - 5. Explain the contributions of Meyer and Moseley...Ch. 8 - Prob. 6ECh. 8 - Prob. 7ECh. 8 - Prob. 8ECh. 8 - Prob. 9ECh. 8 - 10. What is penetration? How does the penetration...Ch. 8 - 11. Why are the sublevels within a principal level...Ch. 8 - 12. What is an orbital diagram? Provide an...Ch. 8 - Prob. 13ECh. 8 - Prob. 14ECh. 8 - Prob. 15ECh. 8 - Prob. 16ECh. 8 - Prob. 17ECh. 8 - Prob. 18ECh. 8 - Prob. 19ECh. 8 - Prob. 20ECh. 8 - 21. Describe the relationship between an element’s...Ch. 8 - 22. Which of the transition elements in the first...Ch. 8 - 23. Describe how to write the electron...Ch. 8 - Prob. 24ECh. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - 27. What is effective nuclear charge? What is...Ch. 8 - Prob. 28ECh. 8 - Prob. 29ECh. 8 - Prob. 30ECh. 8 - Prob. 31ECh. 8 - Prob. 32ECh. 8 - 33. What is ionization energy? What is the...Ch. 8 - 34. What is the general trend in the first...Ch. 8 - 35. What are the exceptions to the periodic trends...Ch. 8 - 36. Examination of the first few successive...Ch. 8 - Prob. 37ECh. 8 - Prob. 38ECh. 8 - 39. Write a general equation for the reaction of...Ch. 8 - Prob. 40ECh. 8 - 41. Write the full electron configuration for each...Ch. 8 - 42. Write the full electron configuration for...Ch. 8 - 43. Write the full orbital diagram for each...Ch. 8 - 44. Write the full orbital diagram for each...Ch. 8 - 45. Use the periodic table to write an electron...Ch. 8 - 46. Use the periodic table to determine the...Ch. 8 - 47. Use the periodic table to determine each...Ch. 8 - 48. Use the periodic table to determine each...Ch. 8 - Name an element in the fourth period (row) of the...Ch. 8 - 50. Name an element in the third period (row) of...Ch. 8 - 51. Determine the number of valence electrons in...Ch. 8 - Prob. 52ECh. 8 - 53. Which outer electron configuration would you...Ch. 8 - Prob. 54ECh. 8 - 55. According to Coulomb’s law, which pair of...Ch. 8 - 56. According to Coulomb’s law, rank the...Ch. 8 - 57. Which of the following will experience a...Ch. 8 - 58. Arrange the atoms according to decreasing...Ch. 8 - 59. If core electrons completely shielded valence...Ch. 8 - Prob. 60ECh. 8 - 61. Choose the larger atom from each pair.
a. Al...Ch. 8 - Prob. 62ECh. 8 - 63. Arrange these elements in order of increasing...Ch. 8 - 64. Arrange these elements in order of decreasing...Ch. 8 - 65. Write the electron configuration for each...Ch. 8 - 66. Write the electron configuration for each...Ch. 8 - 67. Write orbital diagrams for each ion and...Ch. 8 - Prob. 68ECh. 8 - 69. Which is the larger species in each pair?
a....Ch. 8 - 70. Which is the larger species in each pair?
a....Ch. 8 - 71. Arrange this isoelectronic series in order of...Ch. 8 - Prob. 72ECh. 8 - 73. Choose the element with the higher first...Ch. 8 - Prob. 74ECh. 8 - 75. Arrange these elements in order of increasing...Ch. 8 - Prob. 76ECh. 8 - 77. For each element, predict where the “jump”...Ch. 8 - 78. Consider this set of ionization...Ch. 8 - 79. Choose the element with the more negative...Ch. 8 - Prob. 80ECh. 8 - 81. Choose the more metallic element from each...Ch. 8 - Prob. 82ECh. 8 - 83. Arrange these elements in order of increasing...Ch. 8 - Prob. 84ECh. 8 - Prob. 85ECh. 8 - Prob. 86ECh. 8 - Prob. 87ECh. 8 - Prob. 88ECh. 8 - Prob. 89ECh. 8 - Prob. 90ECh. 8 - Prob. 91ECh. 8 - Prob. 92ECh. 8 - Prob. 93ECh. 8 - Prob. 94ECh. 8 - Prob. 95ECh. 8 - Prob. 96ECh. 8 - Prob. 97ECh. 8 - Prob. 98ECh. 8 - 99. Consider these elements: N, Mg, O, F, and...Ch. 8 - Prob. 100ECh. 8 - Prob. 101ECh. 8 - Prob. 102ECh. 8 - Prob. 103ECh. 8 - Prob. 104ECh. 8 - Prob. 105ECh. 8 - 106. The electron affinity of each group 5A...Ch. 8 - 107. The elements with atomic numbers 35 and 53...Ch. 8 - Prob. 108ECh. 8 - Prob. 109ECh. 8 - Prob. 110ECh. 8 - Prob. 111ECh. 8 - 112. The first ionization energy of sodium is 496...Ch. 8 - 115. Consider the densities and atomic radii of...Ch. 8 - 116. As you have seen, the periodic table is a...Ch. 8 - 117. Consider the metals in the first transition...Ch. 8 - 118. Imagine a universe in which the value of ms...Ch. 8 - Prob. 117ECh. 8 - Prob. 118ECh. 8 - Prob. 119ECh. 8 - Prob. 120ECh. 8 - 123. Unlike the elements in groups 1A and 2A,...Ch. 8 - 124. Using the data in Figures 8.15 and 8.16,...Ch. 8 - 125. Even though adding two electrons to O or S...Ch. 8 - Prob. 124ECh. 8 - 127. The heaviest known alkaline earth metal is...Ch. 8 - Prob. 126ECh. 8 - Prob. 127ECh. 8 - Prob. 128ECh. 8 - 131. Imagine that in another universe atoms and...Ch. 8 - 132. The outermost valence electron in atom A...Ch. 8 - 133. Determine whether each statement regarding...Ch. 8 - Prob. 132ECh. 8 - Prob. 133E
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