Concept explainers
Interpretation: Whether the answers in CTQ are in agreement with Memorization Task NW1.2 given below or not should be given.
Concept introduction: Systematic way to name different organic compounds is
Rules for nomenclature of
1 The longest continuous carbon chain is identified first and named in accordance with number of carbon atoms present in it. For example, hydrocarbon with one carbon atom has prefix “meth”, that with two carbon atoms has prefix “eth”, that with three carbon atoms has prefix “prop” and so on. Suffix used for alkanes is “ane.”
2. Substituents attached to parent carbon chain are to be identified. These are named by removal of single hydrogen atom from carbon chain end and named by replacement of suffix “ane” by “yl.” For example if
3. Carbons of parent chain are named in such way that substituents acquire the lowest numbers.
4. If same substituent is present more than one time in molecule, it is represented by prefix “di”, “tri” and so on. It depends on number of times substituent occurs in molecule.
5. If two or more substituents are present in molecule, these are named in alphabetical order.
6. If carbon chains of same length exist in same molecule, chain with the largest number of side chains, followed by lowest number to substituents, chain with the greatest number of carbon atoms in smaller chain and chain with the least branched side chains are preferred over other ones.
7. Prefix “cyclo” is used if cyclic alkane is present in molecule.
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Chapter NW1 Solutions
Organic Chemistry: A Guided Inquiry
- Determine the rate law for sodium thiosulfate from the following data: [Na2S2O3] Time (s) 0.0318 230. 0.0636 57.5arrow_forwardPlease solvearrow_forwardRank the compounds in each group below according to their reactivity toward electrophilic aromatic substitution (most reactive = 1; least reactive = 3). Place the number corresponding to the compounds' relative reactivity in the blank below the compound. a. CH₂F CH3 F b. At what position, and on what ring, is bromination of phenyl benzoate expected to occur? Explain your answer. :0: C-O phenyl benzoate 6.Consider the reaction below to answer the following questions. A B C NO₂ FeBr3 + Br₂ D a. The nucleophile in the reaction is: BODADES b. The Lewis acid catalyst in the reaction is: C. This reaction proceeds d. Draw the structure of product D. (faster or slower) than benzene.arrow_forward
- Part 2. A solution of 6.00g of substance B in 100.0mL of aqueous solution is in equilibrium, at room temperature, wl a solution of B in diethyl ether (ethoxyethane) containing 25.0 g of B in 50.0 mL 9) what is the distribution coefficient of substance B b) what is the mass of B extracted by shaking 200 ml of an aqueous solution containing 10g of B with call at room temp): i) 100 mL of diethyl ether ii) 50ml of diethyl ether twice iii) 25ml of diethyl ether four timesarrow_forward- Rank the following groups of compounds from most acidic (1) to least acidic (4). Place the number corresponding to the compound's relative rank in the blank below the structure. a. NO₂ NO₂ CH2CH2CH2CH2OH CH3 CH3CH2CHOH CH3CH2CH2CH2OH NO₂ CH3CHCH2CH2OH b. OH OH CH₂OH CO₂H HC CN CN CNarrow_forwardGive the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry a. H MgBr 1. ether 2. H₂O* 4 COH b. 1. LIAIH, ether 2. H₂O Choose the best reagent(s) for carrying out the following conversions from the list provided below. Place the letter of the best choice in the blank to the left of the conversion. Reagents may be used more than once. a. 1. CH3MgBr, ether 2. H3O+ NaOH b. 1. PBr3 2. C. 2. 1. (CH3)3SiCl, (CH3CH2)3N CH3MgBr, ether 3. H₂O*+ 2. H3O+ e. 1. p-TosCl, pyridine f. نها g. 2. NaOH CrO3, H₂SO4, H₂O 1. NaBH4, ethanol 2. H30* h. PCC, CH2Cl2 Ovoldo-6 a. b. OH OH H OH O any organicarrow_forward
- Determine the rate law for sodium thiosulfate from the following data: [Na2S2O3] Time (s) 0.0318 230. 0.0636 57.5arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardDetermine the rate order from the following data: [Na2S2O3] Time (s) 0.0455 M 180.0 0.0909 M 90.0 0.136 M 60.0 Group of answer choices First order Second order Third order Zero orderarrow_forward
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning