Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter L, Problem 58GQ
There are five hydrocarbon compounds (compounds of C and II) that have the formula C6H14. (These are isomers; they differ in the way that C and H atoms are attached. Chapter 23) All are liquids at room temperature but have slightly different densities.
(a) You have a pure sample of one of these hydrocarbons, and to identify it you decide to measure its density. You determine that a 5.0-mL sample (measured in a graduated cylinder) has a mass of 3.2745 g (measured on an analytical balance). Assume that the accuracy of the values for mass and volume is plus or minus one (± 1) in the last significant figure. What is the density of the liquid?
(b) Can you identify the unknown hydrocarbon based on your experiment?
(c) Can you eliminate any of the five possibilities based on the data? If so, which one(s)?
(d) You need a more accurate volume measurement to solve this problem, and you redetermine the volume to be 4.93 mL Based on this new informationwhat is the unknown compound?
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Consider the following reactions:CoO (s) + CO (g) D CO2 (g) + Co (s) Kc(1) = 490.2 CoO (s) + 2 H2 (g) D 2 Co (s) + 2 H2O (g) Kc(2) = 4.5 x 103a. Write the overall equation for the reaction of hydrogen gas and carbon dioxide gas to produce carbon monoxide gas and steam.
62. When corn is allowed to ferment, the fructose in the
corn is converted to ethyl alcohol according to the following
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C,H12O6(aq) →2C,H;OH(1) + 2CO2(g)
(a) What volume of ethyl alcohol (d = 0.789 g/mL) is
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(b) Gasohol can be a mixture of 10 mL ethyl alcohol
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7
1.) In the Dumas method for determining the molar mass of an unknown volatile liquid, a sample of a volatile liquid that boils below 100 oC is vaporized in a boiling water bath and the mass of the vapor required to fill the flask is determined. The following data was collected:
Flask Volume
100.0 +100.0 + 79.6 mL = 279.6 mL
Mass of Flask + Cap
143.85 g
Mass of Flask + Condensed Liquid
144.95 g
Mass of Condensed Liquid
1.10 g
Temperature of Water Bath (oC)
84.1 oC
Barometric Pressure (atm)
0.985 atm
a.) What is the molar mass of the unknown?
b.) What will its temperature be when the pressure is 1.20 atm and the volume is 250.0 mL?
Chapter L Solutions
Chemistry & Chemical Reactivity
Ch. L.1 - The distance between two carbon atoms in diamond...Ch. L.1 - Prob. 1RCCh. L.1 - Prob. 2RCCh. L.1 - Prob. 3RCCh. L.1 - Prob. 4RCCh. L.1 - 5. A circulated U.S. quarter has a mass of 5.59 g....Ch. L.1 - Prob. 6RCCh. L.1 - Prob. 7RCCh. L.2 - Two students measured the freezing point of a...Ch. L.2 - Prob. 1RC
Ch. L.2 - Two students were assigned to determine the mass...Ch. L.3 - Prob. 1CYUCh. L.3 - Prob. 1RCCh. L.3 - Prob. 2RCCh. L.3 - 3. What is the sum of 10.26 g and 0.063 g?
10.323...Ch. L.3 - Prob. 4RCCh. L.4 - The density of gold is 19,320 kg/m3. What is this...Ch. L.4 - 1. A lake has an area of 2.33 × 107 m2. What is...Ch. L.5 - What is the fuel density in units of kg/L?Ch. L.5 - What mass and what volume of fuel should have been...Ch. L.6 - A particular paint has a density of 0.914 g/cm3....Ch. L.6 - Prob. 1RCCh. L - Many laboratories use 25C as a standard...Ch. L - The temperature on the surface of the Sun is 5.5 ...Ch. L - Prob. 3PSCh. L - Make the following temperature conversions:Ch. L - A marathon distance race covers distance of 42.195...Ch. L - The average lead pencil, new and unused, is 19 cm...Ch. L - A standard U.S. postage stamp is 2.5 cm long and...Ch. L - A compact disc has a diameter of 11.8 cm. What is...Ch. L - A typical laboratory beaker has a volume of 250....Ch. L - Some soft drinks are sold in bottles with a volume...Ch. L - A book has a mass of 2.52 kg. What is this mass in...Ch. L - A new U.S. dime has a mass of 2.265 g. What is its...Ch. L - Ethylene glycol, C2H6O2, is an ingredient of...Ch. L - A piece of silver metal has a mass of 2.365 g. If...Ch. L - Prob. 15PSCh. L - Which occupies a larger volume, 600 g of water...Ch. L - You are on a diet that calls for eating no more...Ch. L - A 2-in. piece of chocolate cake with frosting...Ch. L - Prob. 19PSCh. L - Prob. 20PSCh. L - You and your lab partner are asked to determine...Ch. L - The accepted value of the melting point of...Ch. L - Prob. 23PSCh. L - Prob. 24PSCh. L - Prob. 25PSCh. L - Prob. 26PSCh. L - To determine the average mass of a popcorn kernel,...Ch. L - Use the following graph to answer the following...Ch. L - Use the graph below to answer the following...Ch. L - Solve the following equation for the unknown...Ch. L - Solve the following equation for the unknown...Ch. L - Solve the following equation for the unknown...Ch. L - Prob. 34PSCh. L - Molecular distances are usually given in...Ch. L - The separation between carbon atoms in diamond is...Ch. L - A red blood cell has a diameter of 7.5 m...Ch. L - The platinum-containing cancer drug cisplatin...Ch. L - Prob. 39GQCh. L - You need a cube of aluminum with a mass of 7.6 g....Ch. L - You have a 250.0-mL graduated cylinder containing...Ch. L - Prob. 42GQCh. L - The smallest repeating unit of a crystal of common...Ch. L - Diamond has a density of 3.513 g/cm3. The mass of...Ch. L - Prob. 45GQCh. L - The density of pure water at various temperatures...Ch. L - Prob. 47GQCh. L - The aluminum in a package containing 75 ft2 of...Ch. L - Fluoridation of city water supplies has been...Ch. L - About two centuries ago, Benjamin Franklin showed...Ch. L - Prob. 51GQCh. L - A 26-meter-tall statue of Buddha in Tibet is...Ch. L - At 25 C, the density of water is 0.997 g/cm3,...Ch. L - Suppose your bedroom is 18 ft long and 15 ft wide,...Ch. L - A spherical steel ball has a mass of 3.475 g and a...Ch. L - You are asked to identify an unknown liquid that...Ch. L - You have an irregularly shaped piece of an unknown...Ch. L - There are five hydrocarbon compounds (compounds of...Ch. L - Suppose you have a cylindrical glass tube with a...Ch. L - Copper: Copper has a density of 8.96 g/cm3 An...Ch. L - Copper: (a) Suppose you have a cube of copper...Ch. L - A sample of unknown metal is placed in a graduated...Ch. L - Iron pyrite is often called fool's gold because it...Ch. L - You can analyze for a copper compound in water...Ch. L - Prob. 67IL
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