
Chemistry & Chemical Reactivity, Hybrid Edition (with OWLv2 24-Months Printed Access Card)
9th Edition
ISBN: 9781285462530
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter L, Problem 31PS
Solve the following equation for the unknown value, C.
(0.502)(123) = (750)C
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Consider the "C NMR spectrum below.
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The spectrum belongs to which one of the following constitutional isomers of the compound C,H12? Select the single best answer.
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
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1
How many signals do you expect in the 'H NMR spectrum for this molecule?
CI CI
Cl
Write the answer in the table below.
Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all
other H atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum.
1
Number of signals in the 'H NMR spectrum.
☐
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same
signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional H atoms to highlight in
top molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the
same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at…
Chapter L Solutions
Chemistry & Chemical Reactivity, Hybrid Edition (with OWLv2 24-Months Printed Access Card)
Ch. L.1 - The distance between two carbon atoms in diamond...Ch. L.1 - Prob. 1RCCh. L.1 - Prob. 2RCCh. L.1 - Prob. 3RCCh. L.1 - Prob. 4RCCh. L.1 - 5. A circulated U.S. quarter has a mass of 5.59 g....Ch. L.1 - Prob. 6RCCh. L.1 - Prob. 7RCCh. L.2 - Two students measured the freezing point of a...Ch. L.2 - Prob. 1RC
Ch. L.2 - Two students were assigned to determine the mass...Ch. L.3 - Prob. 1CYUCh. L.3 - Prob. 1RCCh. L.3 - Prob. 2RCCh. L.3 - 3. What is the sum of 10.26 g and 0.063 g?
10.323...Ch. L.3 - Prob. 4RCCh. L.4 - The density of gold is 19,320 kg/m3. What is this...Ch. L.4 - 1. A lake has an area of 2.33 × 107 m2. What is...Ch. L.5 - What is the fuel density in units of kg/L?Ch. L.5 - What mass and what volume of fuel should have been...Ch. L.6 - A particular paint has a density of 0.914 g/cm3....Ch. L.6 - Prob. 1RCCh. L - Many laboratories use 25C as a standard...Ch. L - The temperature on the surface of the Sun is 5.5 ...Ch. L - Prob. 3PSCh. L - Make the following temperature conversions:Ch. L - A marathon distance race covers distance of 42.195...Ch. L - The average lead pencil, new and unused, is 19 cm...Ch. L - A standard U.S. postage stamp is 2.5 cm long and...Ch. L - A compact disc has a diameter of 11.8 cm. What is...Ch. L - A typical laboratory beaker has a volume of 250....Ch. L - Some soft drinks are sold in bottles with a volume...Ch. L - A book has a mass of 2.52 kg. What is this mass in...Ch. L - A new U.S. dime has a mass of 2.265 g. What is its...Ch. L - Ethylene glycol, C2H6O2, is an ingredient of...Ch. L - A piece of silver metal has a mass of 2.365 g. If...Ch. L - Prob. 15PSCh. L - Which occupies a larger volume, 600 g of water...Ch. L - You are on a diet that calls for eating no more...Ch. L - A 2-in. piece of chocolate cake with frosting...Ch. L - Prob. 19PSCh. L - Prob. 20PSCh. L - You and your lab partner are asked to determine...Ch. L - The accepted value of the melting point of...Ch. L - Prob. 23PSCh. L - Prob. 24PSCh. L - Prob. 25PSCh. L - Prob. 26PSCh. L - To determine the average mass of a popcorn kernel,...Ch. L - Use the following graph to answer the following...Ch. L - Use the graph below to answer the following...Ch. L - Solve the following equation for the unknown...Ch. L - Solve the following equation for the unknown...Ch. L - Solve the following equation for the unknown...Ch. L - Prob. 34PSCh. L - Molecular distances are usually given in...Ch. L - The separation between carbon atoms in diamond is...Ch. L - A red blood cell has a diameter of 7.5 m...Ch. L - The platinum-containing cancer drug cisplatin...Ch. L - Prob. 39GQCh. L - You need a cube of aluminum with a mass of 7.6 g....Ch. L - You have a 250.0-mL graduated cylinder containing...Ch. L - Prob. 42GQCh. L - The smallest repeating unit of a crystal of common...Ch. L - Diamond has a density of 3.513 g/cm3. The mass of...Ch. L - Prob. 45GQCh. L - The density of pure water at various temperatures...Ch. L - Prob. 47GQCh. L - The aluminum in a package containing 75 ft2 of...Ch. L - Fluoridation of city water supplies has been...Ch. L - About two centuries ago, Benjamin Franklin showed...Ch. L - Prob. 51GQCh. L - A 26-meter-tall statue of Buddha in Tibet is...Ch. L - At 25 C, the density of water is 0.997 g/cm3,...Ch. L - Suppose your bedroom is 18 ft long and 15 ft wide,...Ch. L - A spherical steel ball has a mass of 3.475 g and a...Ch. L - You are asked to identify an unknown liquid that...Ch. L - You have an irregularly shaped piece of an unknown...Ch. L - There are five hydrocarbon compounds (compounds of...Ch. L - Suppose you have a cylindrical glass tube with a...Ch. L - Copper: Copper has a density of 8.96 g/cm3 An...Ch. L - Copper: (a) Suppose you have a cube of copper...Ch. L - A sample of unknown metal is placed in a graduated...Ch. L - Iron pyrite is often called fool's gold because it...Ch. L - You can analyze for a copper compound in water...Ch. L - Prob. 67IL
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- wrtie the balanced equation and find the E° when the following half- reactions are combined Zn2+(aq) + 2e---> Zn(s) E°= -0.763V Ag+(aq) + e---> Ag (s) E°=+0.799Varrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forwardStudy this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forward
- how many moles of H2O2 are required to react with 11g of N2H4 according to the following reaction? (atomic weights: N=14.01, H=1.008, O= 16.00) 7H2O2 + N2H4 -> 2HNO3 + 8H20arrow_forwardcalculate the number of moles of H2 produced from 0.78 moles of Ga and 1.92 moles HCL? 2Ga+6HCL->2GaCl3+3H2arrow_forwardan adult human breathes 0.50L of air at 1 atm with each breath. If a 50L air tank at 200 atm is available, how man y breaths will the tank providearrow_forward
- Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1arrow_forwardWhy do we analyse salt?arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H H CH3OH, H+ H Select to Add Arrows H° 0:0 'H + Q HH ■ Select to Add Arrows CH3OH, H* H. H CH3OH, H+ HH ■ Select to Add Arrows i Please select a drawing or reagent from the question areaarrow_forward
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