
(a)
Interpretation: The correct number of significant figure for
Concept Introduction:
Significant of zeroes:
- Zeroes between two other significant digits are significant.
- Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
- Zeroes that are placeholders are not significant.
Rules used for significant figures in calculations:
Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.
Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.
Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.
(a)

Answer to Problem 25PS
Explanation of Solution
In
In
The multiplication of
The number of significant figures should the answer contain is the fewest number of significant figures of the given quantity. Both the quantity possesses same significant figures. Hence, the answer should be written as
(b)
Interpretation: The correct number of significant figure for
Concept Introduction:
Significant of zeroes:
- Zeroes between two other significant digits are significant.
- Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
- Zeroes that are placeholders are not significant.
Rules used for significant figures in calculations:
Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.
Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.
Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.
(b)

Answer to Problem 25PS
Explanation of Solution
In
In
The subtraction of
The number of decimal places should the answer contain is the fewest decimal places of the given quantity. Both the quantity possesses zero decimal places. Hence, the answer should be written as
(c)
Interpretation: The correct number of significant figure for
Concept Introduction:
Significant of zeroes:
- Zeroes between two other significant digits are significant.
- Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
- Zeroes that are placeholders are not significant.
Rules used for significant figures in calculations:
Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.
Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.
Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.
(c)

Answer to Problem 25PS
Explanation of Solution
In
In
The division of
The number of significant figures should the answer contain is the fewest number of significant figures of the given quantity. Out of both the quantity
(d)
Interpretation: The correct number of significant figure for
Concept Introduction:
Significant of zeroes:
- Zeroes between two other significant digits are significant.
- Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
- Zeroes that are placeholders are not significant.
Rules used for significant figures in calculations:
Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.
Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.
Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.
(d)

Answer to Problem 25PS
Explanation of Solution
The division and multiplication of:
Finally, on the multiplication of
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Chapter L Solutions
Chemistry & Chemical Reactivity, Hybrid Edition (with OWLv2 24-Months Printed Access Card)
- A common buffer for stabilizing antibodies is 100 mM Histidine at pH 7.0. Describe the preparation of this buffer beginning with L-Histidine monohydrochloride monohydrate and 1 M NaOH. Be certain to show the buffering reaction that includes the conjugate acid and base.arrow_forwardFina x | Sign X Sign X lab: X Intro X Cop) X a chat x My x Grad xLaur x Laur x a sheg X S Shoj XS SHE X acmillanlearning.com/ihub/assessment/f188d950-dd73-11e0-9572-0800200c9a66/d591b3f2-d5f7-4983-843c-0d00c1c0340b/f2b47861-07c4-4d1b-a1ee-e7db27d6b4ee?actualCourseld=d591b3f2- 5 © Macmillan Learning Organic Chemistry Maxwell presented by Macmillan Learning For the dehydrohalogenation (E2) reaction shown, draw the Zaitsev product, showing the stereochemistry clearly. H H KOH Br EtOH Heat Select Draw Templates More Erase // C H Q Search hp Q2 Q Δ קו Resouarrow_forwardIs the structural form shown possible given the pKa constraints of the side chains?arrow_forward
- on x Fina X Sign X Sign x lab X Intro X Cop X chat X My x Grac x Laur x Laur x ashes x S Shox S SHE x a eve.macmillanlearning.com/ihub/assessment/f188d950-dd73-11e0-9572-0800200c9a66/d591b3f2-d5f7-4983-843c-0d00c1c0340b/f2b47861-07c4-4d1b-a1ee-e7db27d6b4ee?actualCourseld=d591b3f2-c stions estion. ct each urces. +95 Macmillan Learning Draw the product formed by the reaction of potassium t-butoxide with (15,25)-1-bromo-2-methyl-1-phenylbutane (shown). Clearly show the stereochemistry of the product. H BH (CH3)3CO-K+ +100 H3CW (CH3)3COH +85 H3CH2C +95 ossible ↓ Q Search Select Draw Templates More C H 0 bp A Erase 2Q 112 Resouarrow_forwardIdentify the structure of the PTH derivative generated after two rounds of Edman degradation.arrow_forwardUse the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 31 0.5 30 26 29 22 28 100 27 33 26 23 15 4 • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. 妊 n ? Previous Nextarrow_forward
- for this question. Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 98.1106. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 1.008 12C 98.90 12.000 14N 99.63 14.003 160 99.76 15.995 Molecular formula (In the order CHNO, with no subscripts)arrow_forwardPLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS!!! PLEASE I UNDERSTAND THE BASICS BUT THIS IS AN EXCEPTION THAT EVEN THE INTERNET CANT HELP!!!! THIS IS THE THIRD TIME I'VE SENT THOSE QUESTIONS SO PLEASE DONT RESEND THE SAME STUFF, ITS NOT HELPING ME!!! I ALSO ALREADY TRIED TO DRAW THE MECHANISM MYSELF, SO IF ITS RIGHT PLEASE TELL ME OR TELL ME WHAT I HAVE TO CHANGE!!! First image: I have to SHOW (DRAWING) the mechanism (with arows and structures of molecules) NOT WORDS PLEASE! of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary Second image: I have to show the mechanism (IMAGE) (with arrows and structures of the molecules) NOT WORDS PLEASE !! for the reaction on the left, where the alcohol A is added fast in one portion HOMEWORK, NOT EXAM!! ALL DETAILS ARE IN THE IMAGES PLEASE LOOK AT THE IMAGES, DONT LOOK AT THE AI GENERATED TEXT!!!arrow_forwardWrite the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 85.0899. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 1.008 12C 98.90 12.000 14N 99.63 14.003 160 99.76 15.995 Molecular formula (In the order CHNO, with no subscripts)arrow_forward
- Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 59 3.0 58 64 43 100 15 23 • You do not have to consider stereochemistry. •You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. + n[] 85 // ? CH4 Previous Nextarrow_forwardWrite the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M* = 128.0632. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 12C 98.90 14N 99.63 160 99.76 Molecular formula 1.008 12.000 14.003 15.995 (In the order CHNO, with no subscripts)arrow_forwardCan I please get help with this? And can I please the lowest possible significant number?arrow_forward
- Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning


