(a) Interpretation: The structure from the given IUPAC name is to be drawn. Concept introduction: The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group . The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms. Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

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Answer 1

Question

Chapter F, Problem F.35P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(e)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Complete the spectroscopy with structure

Answer 2

Question

Chapter F, Problem F.35P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(e)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 3

Question

Chapter F, Problem F.35P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(e)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 4

Question

Chapter F, Problem F.35P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(e)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 5

Chapter F, Problem F.35P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Interpretation Introduction

(e)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 6

Chapter F, Problem F.35P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

Answer 7

Chapter F, Problem F.35P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. F - Prob. F.1P Ch. F - Prob. F.2P Ch. F - Prob. F.3P Ch. F - Prob. F.4P Ch. F - Prob. F.5P Ch. F - Prob. F.6P Ch. F - Prob. F.7P Ch. F - Prob. F.8P Ch. F - Prob. F.9P Ch. F - Prob. F.10P

Solution Summary: The structure for IUPAC name 2, 2-Dimethylpropyl hex-3-ynoate is drawn by identifying the highest priority functional group from the suffix, main chain from

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