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(a)
Interpretation:
For the given molecule, the IUPAC is to be written.
Concept introduction:
The IUPAC name of an amide is made of two parts. The first part is based on the number of carbons in the longest continuous carbon chain of the
If any chiral carbons are present, their absolute configurations are determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.
(b)
Interpretation:
For the given molecule, the IUPAC is to be written.
Concept introduction:
The IUPAC name of an amide is made of two parts. The first part is based on the number of carbons in the longest continuous carbon chain of the carboxylic acid from which the amide is derived. This may include the names of any substituents present as a prefix. The final e in the name of the root alkane is replaced by the functional group suffix ‘amide’. If the alkyl part of the root is a cyclic alkane, the root name is cycloalkanecarboxamide.
If any chiral carbons are present, their absolute configurations are determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.
(c)
Interpretation:
For the given molecule, the IUPAC is to be written.
Concept introduction:
The IUPAC name of an amide is made of two parts. The first part is based on the number of carbons in the longest continuous carbon chain of the carboxylic acid from which the amide is derived. This may include the names of any substituents present as a prefix. The final e in the name of the root alkane is replaced by the functional group suffix ‘amide’.
If any chiral carbons are present, their absolute configurations are determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.
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Chapter F Solutions
Organic Chemistry: Principles And Mechanisms
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- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
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