Concept explainers
(a)
Interpretation:
The structure of the given molecule is to be drawn.
Concept introduction:
The structure of a compound is drawn from its IUPAC name. The IUPAC name is made up of three parts, prefix, root, and suffix. The suffix indicates the highest priority functional group present in the structure. Its location is written as a prefix for the functional group name, unless redundant. The root is the longest continuous carbon chain or the largest ring that includes the highest priority functional group. Any other
If any chiral carbons are present, their absolute configurations are specified at the start, along with the carbon number, if necessary. Similarly, the stereochemistry (E/Z) of any double bond is also specified at the start. A di, tri, etc., before a prefix or suffix, indicates the number of instances of that functional group.
(b)
Interpretation:
The structure of the given molecule is to be drawn.
Concept introduction:
The structure of a compound is drawn from its IUPAC name. The IUPAC name is made up of three parts, prefix, root, and suffix. The suffix indicates the highest priority functional group present in the structure. Its location is written as a prefix for the functional group name, unless redundant. The root is the longest continuous carbon chain or the largest ring that includes the highest priority functional group. Any other functional groups present are listed alphabetically as prefixes along with their locants. For cyclic compounds, the numbering starts from that carbon where the highest priority group is attached. If any chiral carbons are present, their absolute configurations are specified at the start, along with the carbon number, if necessary. Similarly, the stereochemistry (E/Z) of any double bond is also specified at the start. A di, tri, etc., before a prefix or suffix, indicates the number of instances of that functional group.
(c)
Interpretation:
The structure of the given molecule is to be drawn.
Concept introduction:
The structure of a compound is drawn from its IUPAC name. The IUPAC name is made up of three parts, prefix, root, and suffix. The suffix indicates the highest priority functional group present in the structure. Its location is written as a prefix for the functional group name, unless redundant. The root is the longest continuous carbon chain or the largest ring that includes the highest priority functional group. Any other functional groups present are listed alphabetically as prefixes along with their locants. For cyclic compounds, the numbering starts from that carbon where the highest priority group is attached.
If any chiral carbons are present, their absolute configurations are specified at the start, along with the carbon number, if necessary. Similarly, the stereochemistry (E/Z) of any double bond is also specified at the start. A di, tri, etc., before a prefix or suffix, indicates the number of instances of that functional group.

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Chapter F Solutions
Organic Chemistry: Principles And Mechanisms
- Tarrow_forwardPredict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.arrow_forward(c) (4pts) Mechanism: heat (E1) CH3OH + 1.5pts each _E1 _ (1pt) Br CH3OH (d) (4pts) Mechanism: SN1 (1pt) (e) (3pts) 1111 I H 10 Ill!! H LDA THF (solvent) Mechanism: E2 (1pt) NC (f) Bri!!!!! CH3 NaCN (3pts) acetone Mechanism: SN2 (1pt) (SN1) -OCH3 OCH3 1.5pts each 2pts for either product 1pt if incorrect stereochemistry H Br (g) “,、 (3pts) H CH3OH +21 Mechanism: SN2 (1pt) H CH3 2pts 1pt if incorrect stereochemistry H 2pts 1pt if incorrect stereochemistryarrow_forward
- A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixturearrow_forwardQ5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R Harrow_forwardCalculate the proton and carbon chemical shifts for this structurearrow_forward
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