(a) Interpretation: The molecule that corresponds to given trivial name is to be drawn. Concept introduction: The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone . When two different alkyl groups are attached to the carbonyl group of ketone , each alkyl group is written and they are separated by a space.

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Answer 1

Question

Chapter E, Problem E.42P

Interpretation Introduction

(a)

Interpretation:

The molecule that corresponds to given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(b)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(c)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(d)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(e)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.

b. CH3 H3C CH3 CH3 H3C an unexpected product, containing a single 9- membered ring the expected product, containing two fused rings H3C-I (H3C)2CuLi an enolate

Answer 2

Question

Chapter E, Problem E.42P

Interpretation Introduction

(a)

Interpretation:

The molecule that corresponds to given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(b)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(c)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(d)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(e)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

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Answer 3

Question

Chapter E, Problem E.42P

Interpretation Introduction

(a)

Interpretation:

The molecule that corresponds to given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(b)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(c)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(d)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(e)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

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Answer 4

Question

Chapter E, Problem E.42P

Interpretation Introduction

(a)

Interpretation:

The molecule that corresponds to given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(b)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(c)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(d)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(e)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

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Answer 5

Chapter E, Problem E.42P

Interpretation Introduction

(a)

Interpretation:

The molecule that corresponds to given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(b)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(c)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(d)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Interpretation Introduction

(e)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 6

Chapter E, Problem E.42P

Interpretation Introduction

(a)

Interpretation:

The molecule that corresponds to given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 7

Chapter E, Problem E.42P

Interpretation Introduction

(a)

Interpretation:

The molecule that corresponds to given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The molecule that corresponds to the given trivial name is to be drawn.

Concept introduction:

The ketones consist of two alkyl or aryl groups attached to a carbonyl (C=O) group. The trivial name of ketone consists of identifying the alkyl or aryl groups and listing them both before the word ketone. When two different alkyl groups are attached to the carbonyl group of ketone, each alkyl group is written and they are separated by a space.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains the structure of the ketone molecule that corresponds to given trivial name.

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