Concept explainers
Videos
(a)
Interpretation:
The complete structure is to be drawn, and the IUPAC name is to be provided for the given trivial name.
Concept introduction:
Trivial names of
The IUPAC name of an amine consists of three parts. The root is the largest alkyl group or the aryl group to which the amine group is attached. The location of the amine group on the root is established by numbering the chain so that it gets the lowest possible number. Any other alkyl/aryl groups bonded to nitrogen is treated as a substituent on the nitrogen. They are listed as prefixes in alphabetical order.
(b)
Interpretation:
The complete structure is to be drawn and IUPAC name is to be provided for the given trivial name.
Concept introduction:
Trivial names of amines consist of the trivial names of the alkyl/aryl groups bonded to the nitrogen atom, followed by the functional group name ‘amine’.
IUPAC name of an amine consists of three parts. The root is the largest alkyl/aryl group bonded to the nitrogen. The location of the amine group on the root is established by numbering the chain or ring so that it gets the lowest possible number. Any other alkyl/aryl groups bonded to the nitrogen is treated as substituents on the nitrogen atom. They are listed as prefixes in alphabetical order.
(c)
Interpretation:
The complete structure is to be drawn and IUPAC name is to be provided for
Concept introduction:
Trivial names of amines consist of the trivial names of the alkyl/aryl groups attached to the nitrogen, followed by the functional group name ‘amine’.
The IUPAC name consists of three parts. The suffix is amine. The largest alkyl/aryl group attached to nitrogen determines the root name. Any other alkyl/aryl groups attached to nitrogen is treated as substituent on the nitrogen atom and listed alphabetically as prefixes.
(d)
Interpretation:
The complete structure is to be drawn and IUPAC name is to be provided for triethylamine.
Concept introduction:
Trivial names of amines consist of the trivial names of the alkyl/aryl groups attached to the nitrogen, followed by the functional group name ‘amine’.
The IUPAC name consists of three parts. The suffix is amine. The largest alkyl/aryl group attached to nitrogen determines the root name. Any other alkyl/aryl groups attached to nitrogen is treated as substituent on nitrogen and listed alphabetically as prefixes.
(e)
Interpretation:
The complete structure is to be drawn and IUPAC name is to be provided for diphenylamine.
Concept introduction:
Trivial names of amines consist of the trivial names of the alkyl/aryl groups attached to the nitrogen, followed by the functional group name ‘amine’.
The IUPAC name consists of three parts. The suffix is amine. The largest alkyl/aryl group attached to the nitrogen determines the root name. Any other alkyl/aryl groups attached to nitrogen is treated as substituent on nitrogen, and listed alphabetically.
Want to see the full answer?
Check out a sample textbook solution
Chapter E Solutions
Organic Chemistry: Principles And Mechanisms (second Edition)
- on x Fina X Sign X Sign x lab X Intro X Cop X chat X My x Grac x Laur x Laur x ashes x S Shox S SHE x a eve.macmillanlearning.com/ihub/assessment/f188d950-dd73-11e0-9572-0800200c9a66/d591b3f2-d5f7-4983-843c-0d00c1c0340b/f2b47861-07c4-4d1b-a1ee-e7db27d6b4ee?actualCourseld=d591b3f2-c stions estion. ct each urces. +95 Macmillan Learning Draw the product formed by the reaction of potassium t-butoxide with (15,25)-1-bromo-2-methyl-1-phenylbutane (shown). Clearly show the stereochemistry of the product. H BH (CH3)3CO-K+ +100 H3CW (CH3)3COH +85 H3CH2C +95 ossible ↓ Q Search Select Draw Templates More C H 0 bp A Erase 2Q 112 Resouarrow_forwardIdentify the structure of the PTH derivative generated after two rounds of Edman degradation.arrow_forwardUse the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 31 0.5 30 26 29 22 28 100 27 33 26 23 15 4 • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. 妊 n ? Previous Nextarrow_forward
- for this question. Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 98.1106. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 1.008 12C 98.90 12.000 14N 99.63 14.003 160 99.76 15.995 Molecular formula (In the order CHNO, with no subscripts)arrow_forwardPLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS!!! PLEASE I UNDERSTAND THE BASICS BUT THIS IS AN EXCEPTION THAT EVEN THE INTERNET CANT HELP!!!! THIS IS THE THIRD TIME I'VE SENT THOSE QUESTIONS SO PLEASE DONT RESEND THE SAME STUFF, ITS NOT HELPING ME!!! I ALSO ALREADY TRIED TO DRAW THE MECHANISM MYSELF, SO IF ITS RIGHT PLEASE TELL ME OR TELL ME WHAT I HAVE TO CHANGE!!! First image: I have to SHOW (DRAWING) the mechanism (with arows and structures of molecules) NOT WORDS PLEASE! of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary Second image: I have to show the mechanism (IMAGE) (with arrows and structures of the molecules) NOT WORDS PLEASE !! for the reaction on the left, where the alcohol A is added fast in one portion HOMEWORK, NOT EXAM!! ALL DETAILS ARE IN THE IMAGES PLEASE LOOK AT THE IMAGES, DONT LOOK AT THE AI GENERATED TEXT!!!arrow_forwardWrite the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 85.0899. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 1.008 12C 98.90 12.000 14N 99.63 14.003 160 99.76 15.995 Molecular formula (In the order CHNO, with no subscripts)arrow_forward
- Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 59 3.0 58 64 43 100 15 23 • You do not have to consider stereochemistry. •You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. + n[] 85 // ? CH4 Previous Nextarrow_forwardWrite the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M* = 128.0632. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 12C 98.90 14N 99.63 160 99.76 Molecular formula 1.008 12.000 14.003 15.995 (In the order CHNO, with no subscripts)arrow_forwardCan I please get help with this? And can I please the lowest possible significant number?arrow_forward
- What is the molar mass of a gas that takes three times longer to effuse than helium?arrow_forwardFirst image: I have to show the mecanism (with arows and structures) of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary Second image: I have to show the mecanism (with arrows and structures) for the reaction on the left, where the alcohol A is added fast in one portion its not an examarrow_forwardwhat is the skeletal structure of a tertiary alkyl fluoride with six carbon atoms and no rings.arrow_forward
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning