The atomic orbital overlap and MO energy diagrams for CH 3 Cl are to be constructed, and its LUMO is to be determined from these diagrams. Concept introduction: Molecular orbitals are constructed from the AOs of different atoms. When two atoms are brought close enough together (i.e., about a bond length apart), the AOs of one atom significantly overlap the AOs of the other atom, enabling them to undergo constructive and destructive interference or mix, to produce new orbitals called MOs. When AOs undergo mixing to produce new MOs, there are equal numbers of bonding and antibonding orbitals, and the remaining orbitals are represented by nonbonding orbitals. In carbocation, the positively charged carbon is sp 2 hybridized and uses these sp 2 orbitals for bonding with other three substituents while the normal C atom is sp 3 hybridized, and the H atom contributes its s orbital.

Question

Want to see the full answer?

Answer 1

Question

Chapter D, Problem D.7YT

Interpretation Introduction

Interpretation:

The atomic orbital overlap and MO energy diagrams for CH3Cl are to be constructed, and its LUMO is to be determined from these diagrams.

Concept introduction:

Molecular orbitals are constructed from the AOs of different atoms. When two atoms are brought close enough together (i.e., about a bond length apart), the AOs of one atom significantly overlap the AOs of the other atom, enabling them to undergo constructive and destructive interference or mix, to produce new orbitals called MOs. When AOs undergo mixing to produce new MOs, there are equal numbers of bonding and antibonding orbitals, and the remaining orbitals are represented by nonbonding orbitals. In carbocation, the positively charged carbon is sp2 hybridized and uses these sp2 orbitals for bonding with other three substituents while the normal C atom is sp3 hybridized, and the H atom contributes its s orbital.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

2H2S(g)+3O2(g)→2SO2(g)+2H2O(g) A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion. Question Which of the following predicts the theoretical yield of SO2(g) from the reaction? Responses 1.2 g Answer A: 1.2 grams A 41 g Answer B: 41 grams B 77 g Answer C: 77 grams C 154 g Answer D: 154 grams D

Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Q: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCC