ORG CHEM W/ EBOOK & SW5 + STUDY GUIDE
ORG CHEM W/ EBOOK & SW5 + STUDY GUIDE
2nd Edition
ISBN: 9780393666144
Author: KARTY
Publisher: NORTON
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Chapter D, Problem D.8P
Interpretation Introduction

Interpretation:

It is to be shown that the electrophilic addition involving CH3CH=CHCH3 and (CH3)3C+ is allowed.

Concept introduction:

When two orbitals overlap with the same phases, constructive interference takes place. When two orbitals overlap with the opposite phases, destructive interference takes place. Constructive interference results in a new orbital that is more stable than the σ bonding orbital, and destructive interference results in a new orbital that is less stable than the p atomic orbital.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
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