EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
2nd Edition
ISBN: 9780393630817
Author: KARTY
Publisher: W.W.NORTON+CO. (CC)
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Chapter C, Problem C.16P
Interpretation Introduction

(a)

Interpretation:

The structure for each of the given name is to be drawn.

Concept introduction:

In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond, which is a part of the ring, can have E or Z configuration.

If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.

Interpretation Introduction

(b)

Interpretation:

The structure for each of the given name is to be drawn.

Concept introduction:

In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond, which is a part of the ring, can have E or Z configuration.

If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.

Interpretation Introduction

(c)

Interpretation:

The structure for each of the given name is to be drawn.

Concept introduction:

In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond which is a part of the ring can have E or Z configuration.

If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.

Interpretation Introduction

(d)

Interpretation:

The structure for each of the given name is to be drawn.

Concept introduction:

In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond which is a part of the ring can have E or Z configuration.

If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.

Interpretation Introduction

(e)

Interpretation:

The structure for the given name is to be drawn.

Concept introduction:

In case of rings containing seven or less than seven carbon atoms, the Z/E configuration is usually omitted for the double bonds which are a part of the ring. The E configuration about the double bond is not stable due to ring strain. It is understood that the double bonded carbon atoms have a configuration such that they are cis to each other. In case of rings consisting of more than seven carbon atoms, the double bond which is a part of the ring can have E or Z configuration.

If the higher priority groups, attached to the double bonded carbon atoms, are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups, attached to the double bonded carbon atoms, are on the opposite side of the double bond, the alkene is assigned E configuration.

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