INSTRUMENTAL ANALYSIS-ACCESS >CUSTOM<
7th Edition
ISBN: 9781337783439
Author: Skoog
Publisher: CENGAGE C
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Chapter A1, Problem A1.16QAP
Interpretation Introduction
Interpretation:
In a NIST reference steel sample the certified percentage of nickel is 1.12% and the standard deviation related to this 0.03%. The determination of percentage produce for the nickel using new spectrometric method is − 1.10, 1.08, 1.09, 1.12 and 1.09. The indication of the bias in the method at the 95% level is to be determined.
Concept introduction:
The formula that will be used-
Here,
N = degree of freedom
s = standard deviation
t = constant
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
200
160
120
80
40
0
200
160
120
80
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0
DEPT 135
T
200
160
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Draw the unknown amide.
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Chapter A1 Solutions
INSTRUMENTAL ANALYSIS-ACCESS >CUSTOM<
Ch. A1 - Prob. A1.1QAPCh. A1 - Prob. A1.2QAPCh. A1 - Prob. A1.3QAPCh. A1 - Prob. A1.4QAPCh. A1 - Prob. A1.5QAPCh. A1 - Prob. A1.6QAPCh. A1 - Prob. A1.7QAPCh. A1 - Prob. A1.8QAPCh. A1 - Prob. A1.9QAPCh. A1 - Prob. A1.10QAP
Ch. A1 - Prob. A1.11QAPCh. A1 - Prob. A1.12QAPCh. A1 - Prob. A1.13QAPCh. A1 - Prob. A1.14QAPCh. A1 - Prob. A1.15QAPCh. A1 - Prob. A1.16QAPCh. A1 - Prob. A1.17QAPCh. A1 - Prob. A1.18QAPCh. A1 - Prob. A1.19QAPCh. A1 - Prob. A1.20QAPCh. A1 - Prob. A1.21QAPCh. A1 - Prob. A1.22QAPCh. A1 - Prob. A1.23QAPCh. A1 - Prob. A1.24QAP
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