Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Question
Chapter A1, Problem A1.16QAP
Interpretation Introduction
Interpretation:
In a NIST reference steel sample the certified percentage of nickel is 1.12% and the standard deviation related to this 0.03%. The determination of percentage produce for the nickel using new spectrometric method is − 1.10, 1.08, 1.09, 1.12 and 1.09. The indication of the bias in the method at the 95% level is to be determined.
Concept introduction:
The formula that will be used-
Here,
N = degree of freedom
s = standard deviation
t = constant
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Students have asked these similar questions
What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter A1 Solutions
Principles of Instrumental Analysis
Ch. A1 - Prob. A1.1QAPCh. A1 - Prob. A1.2QAPCh. A1 - Prob. A1.3QAPCh. A1 - Prob. A1.4QAPCh. A1 - Prob. A1.5QAPCh. A1 - Prob. A1.6QAPCh. A1 - Prob. A1.7QAPCh. A1 - Prob. A1.8QAPCh. A1 - Prob. A1.9QAPCh. A1 - Prob. A1.10QAP
Ch. A1 - Prob. A1.11QAPCh. A1 - Prob. A1.12QAPCh. A1 - Prob. A1.13QAPCh. A1 - Prob. A1.14QAPCh. A1 - Prob. A1.15QAPCh. A1 - Prob. A1.16QAPCh. A1 - Prob. A1.17QAPCh. A1 - Prob. A1.18QAPCh. A1 - Prob. A1.19QAPCh. A1 - Prob. A1.20QAPCh. A1 - Prob. A1.21QAPCh. A1 - Prob. A1.22QAPCh. A1 - Prob. A1.23QAPCh. A1 - Prob. A1.24QAP
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