(a) Interpretation: The structure for the given IUPAC name is to be drawn. Concept introduction: An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Question

יווי 10 20 30 40 50 60 70 3.5 3 2.5 2 1.5 1 [ppm] 3.5 3 2.5 2 1.5 1 6 [ppm] 1 1.5 -2.5 3.5

Answer 1

Question

Chapter A, Problem A.23P

Interpretation Introduction

(a)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

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יווי 10 20 30 40 50 60 70 3.5 3 2.5 2 1.5 1 [ppm] 3.5 3 2.5 2 1.5 1 6 [ppm] 1 1.5 -2.5 3.5

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 2

Question

Chapter A, Problem A.23P

Interpretation Introduction

(a)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

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Answer 3

Question

Chapter A, Problem A.23P

Interpretation Introduction

(a)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

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Answer 4

Question

Chapter A, Problem A.23P

Interpretation Introduction

(a)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

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Answer 5

Chapter A, Problem A.23P

Interpretation Introduction

(a)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(b)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Interpretation Introduction

(c)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Answer 6

Chapter A, Problem A.23P

Interpretation Introduction

(a)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Answer 7

Chapter A, Problem A.23P

Interpretation Introduction

(a)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure for the given IUPAC name is to be drawn.

Concept introduction:

An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which the substituents are attached.

Answer 12

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Answer 23

Ch. A - Prob. A.1P Ch. A - Prob. A.2P Ch. A - Prob. A.3P Ch. A - Prob. A.4P Ch. A - Prob. A.5P Ch. A - Prob. A.6P Ch. A - Prob. A.7P Ch. A - Prob. A.8P Ch. A - Prob. A.9P Ch. A - Prob. A.10P

Solution Summary: The author explains the structure for the given IUPAC name. The root defines the number of carbon atoms in the longest chain.

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Chapter A Solutions