ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 9.7, Problem 8P
Interpretation Introduction

Interpretation:

Using the given compounds and any other necessary organic and inorganic reagents, the preparation of propyne by writing appropriate series of equation is to be shown.

Concept Introduction:

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Alkynes can be prepared by alkylation of acetylene.

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Double dehydrohalogenation of either vicinal or geminaldihalides also produces alkynes.

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Vicinal dihalides are prepared by addition of halogens to alkenes.

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Alkenes in turn can be prepared from alcohols by acid catalyzed dehydration.

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Alkenes can also be prepared by elimination reactions of alkyl halides.

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.. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show ll relevant stereochemistry [3 ONLY]. A H Br 1. NaCN 2 NaOH, H₂O, heat 3. H3O+ B. CH₂COOH 19000 1. LiAlH4 THF, heat 2 H₂O* C. CH Br 1. NaCN, acetone 2 H3O+, heat D. Br 1. Mg. ether 3. H₂O+ 2 CO₂ E. CN 1. (CH) CHMgBr, ether 2 H₂O+

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