ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 9, Problem 39DSP
Interpretation Introduction

Interpretation:

The selection of the compound that describes the reaction mechanism that takes place in the first step of the given reaction is to be determined.

Concept Introduction:

Alkynes are produced by both electrophilic and nucleophilic reaction. During the electrophilic reaction, the E2 reaction mechanism pathway is followed and in nucleophilic, SN2 mechanism is followed. Alkynes are associated with triple bond therefore; their properties are vastly different for that of alkene and alkane. Alkynes have high electron density hence, favors electrophilic addition reaction.

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.. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show ll relevant stereochemistry [3 ONLY]. A H Br 1. NaCN 2 NaOH, H₂O, heat 3. H3O+ B. CH₂COOH 19000 1. LiAlH4 THF, heat 2 H₂O* C. CH Br 1. NaCN, acetone 2 H3O+, heat D. Br 1. Mg. ether 3. H₂O+ 2 CO₂ E. CN 1. (CH) CHMgBr, ether 2 H₂O+

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