Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 9.6, Problem 9.10P
Interpretation Introduction
Interpretation:
Concentration in
Concept Introduction:
In order to express the concentration, many units have been used. One among them is parts per million
Expressed as,
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Draw out the following peptide H-R-K-E-D at physiological pH (~7.4). Make sure toreference table 3.1 for pKa values.
The table provides the standard reduction potential, E', for relevant half-cell reactions.
Half-reaction
E'° (V)
Oxaloacetate² + 2H+ + 2e malate²-
-0.166
Pyruvate + 2H+ + 2e → lactate
-0.185
Acetaldehyde + 2H+ + 2e¯ →→→ ethanol
-0.197
NAD+ + H+ + 2e--> NADH
-0.320
NADP+ + H+ + 2e →→ NADPH
Acetoacetate + 2H+ + 2e¯
-
-0.324
B-hydroxybutyrate
-0.346
Which of the reactions listed would proceed in the direction shown, under standard conditions, in the presence of the
appropriate enzymes?
Malate + NAD+ oxaloacetate + NADH + H+
Malate + pyruvate oxaloacetate + lactate
Pyruvate + NADH + H+ lactate + NAD+
Pyruvate + p-hydroxybutyrate lactate + acetoacetate
Acetaldehyde + succinate ethanol + fumerate
Acetoacetate + NADH + H+ → B-hydroxybutyrate + NAD+
Arrange the four structures in order from most reduced to most oxidized.
Most reduced
R-CH2-CH3
R-CH2-CH₂-OH
R-CH,-CHO
R-CH₂-COO
Most oxidized
Chapter 9 Solutions
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Ch. 9.1 - Classify the following liquid mixtures as...Ch. 9.2 - Write the formula of sodium sulfate decahydrate,...Ch. 9.2 - What mass of Glaubers salt must be used to provide...Ch. 9.2 - Which of the following pairs of substances would...Ch. 9.4 - A solution is prepared by dissolving 12.5 g of KBr...Ch. 9.5 - Prob. 9.4PCh. 9.5 - Prob. 9.5PCh. 9.6 - How does the body increase oxygen availability at...Ch. 9.6 - A metal alloy contains 15.8% nickel (m/m)%. What...Ch. 9.6 - Prob. 9.7P
Ch. 9.6 - Prob. 9.8PCh. 9.6 - Prob. 9.9PCh. 9.6 - Prob. 9.10PCh. 9.6 - Prob. 9.11PCh. 9.6 - What is the molarity of a solution that contains...Ch. 9.6 - How many moles of solute are present in the...Ch. 9.6 - The concentration of cholesterol (C27H46O) in...Ch. 9.6 - Prob. 9.15PCh. 9.7 - Prob. 9.16PCh. 9.7 - Prob. 9.17PCh. 9.8 - Prob. 9.5CIAPCh. 9.8 - Prob. 9.6CIAPCh. 9.8 - Prob. 9.7CIAPCh. 9.8 - Prob. 9.18PCh. 9.8 - Prob. 9.19PCh. 9.9 - A solution is prepared by dissolving 0.67 mol of...Ch. 9.9 - Prob. 9.21PCh. 9.9 - Prob. 9.22KCPCh. 9.9 - What is the freezing point of a solution of 1.0...Ch. 9.9 - Prob. 9.24PCh. 9.10 - What is the osmolarity of the following solutions?...Ch. 9.10 - Prob. 9.26PCh. 9.11 - Prob. 9.8CIAPCh. 9.11 - Prob. 9.9CIAPCh. 9 - Assume that two liquids are separated by a...Ch. 9 - Prob. 9.28UKCCh. 9 - Prob. 9.29UKCCh. 9 - Assume that you have two full beakers, one...Ch. 9 - A beaker containing 150.0 mL of 0.1 M glucose is...Ch. 9 - Prob. 9.32APCh. 9 - Prob. 9.33APCh. 9 - Prob. 9.34APCh. 9 - Prob. 9.35APCh. 9 - Which of the following are solutions? (a)Italian...Ch. 9 - Prob. 9.37APCh. 9 - The solubility of NH3 gas in water at an NH3...Ch. 9 - Prob. 9.39APCh. 9 - Is a solution highly concentrated if it is...Ch. 9 - How is mass/volume percent concentration defined...Ch. 9 - Prob. 9.42APCh. 9 - Prob. 9.43APCh. 9 - A 750.0 mL bottle of Listerine is of a 21% (v/v)...Ch. 9 - Prob. 9.45APCh. 9 - Prob. 9.46APCh. 9 - Prob. 9.47APCh. 9 - Prob. 9.48APCh. 9 - Prob. 9.49APCh. 9 - How many moles of each substance are needed to...Ch. 9 - Prob. 9.51APCh. 9 - If you had only 23 g of KOH remaining in a bottle,...Ch. 9 - Prob. 9.53APCh. 9 - The lethal dosage of potassium cyanide (KCN) in...Ch. 9 - What is the molarity of the following solutions?...Ch. 9 - How many grams of solute are in the following...Ch. 9 - How many milliliters of a 0.75 M HCl solution do...Ch. 9 - Prob. 9.58APCh. 9 - Prob. 9.59APCh. 9 - Sodium thiosulfate (Na2S2O3), the major component...Ch. 9 - Prob. 9.61APCh. 9 - What is the final volume of NaOH solution prepared...Ch. 9 - Prob. 9.63APCh. 9 - What is the concentration of a NaCl solution, in...Ch. 9 - Concentrated (12.0 M) hydrochloric acid is sold...Ch. 9 - Dilute solutions of NaHCO3 are sometimes used in...Ch. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - Prob. 9.69APCh. 9 - What is the total anion concentration (in mEq/L)...Ch. 9 - Kaochlor, a 10% (m/v) KCl solution, is an oral...Ch. 9 - Prob. 9.72APCh. 9 - The concentration of Cl ion in blood is...Ch. 9 - Prob. 9.74APCh. 9 - Which lowers the freezing point of 2.0 kg of water...Ch. 9 - Which solution has the higher boiling point, 0.500...Ch. 9 - Methanol, CH3OH, is sometimes used as an...Ch. 9 - Hard candy is prepared by dissolving pure sugar...Ch. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Which of the following solutions has the higher...Ch. 9 - Which of the following solutions will give rise to...Ch. 9 - A pickling solution for preserving food is...Ch. 9 - Prob. 9.84APCh. 9 - Prob. 9.85CPCh. 9 - Emergency treatment of cardiac arrest victims...Ch. 9 - Nitric acid, HNO3, is available commercially at a...Ch. 9 - Prob. 9.88CPCh. 9 - A typical dosage of statin drugs for the treatment...Ch. 9 - Prob. 9.90CPCh. 9 - Prob. 9.91CPCh. 9 - Prob. 9.92CPCh. 9 - Prob. 9.93CPCh. 9 - Prob. 9.94CPCh. 9 - Prob. 9.95CPCh. 9 - Prob. 9.96GPCh. 9 - Look up the maximum concentrations set by the U.S....Ch. 9 - Look up the composition of Ringers solution used...Ch. 9 - To prevent accumulation of ice on roads and...Ch. 9 - Many carbonate minerals are insoluble in water and...Ch. 9 - Prob. 9.101GP
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- for each pair of biomolecules, identify the type of reaction (oxidation-reduction, hydrolysis, isomerization, group transfer, or nternal rearrangement) required to convert the first molecule to the second. In each case, indicate the general type of enzyme and cofactor(s) c reactants required, and any other products that would result. R-CH-CH-CH-C-S-COA A(n) A(n) A(n) A(n) Palmitoyl-CoA R-CH-CH=CH-C-S-CoA ° trans-A-Enoyl-CoA reaction converts palmitoyl-CoA to trans-A2-enoyl-CoA. This reaction requires and also produces Coo HN-C-H CH₂ CH₂ CH CH CH, CH, L-Leucine CH, CH, D-Leucine 8/6881 COO HÌNH: reaction converts L-leucine to D-leucine. This reaction is catalyzed by a(n) H-C-OH H-C-OH C=0 HO-C-H HO-C-H H-C-OH H-C-OH H-C-OH CH,OH Glucose H-C-OH CH,OH Fructose OH OH OH CH-C-CH₂ reaction converts glucose to fructose. This reaction is catalyzed by a(n) OH OH OPO I CH-C-CH H Glycerol Glycerol 3-phosphate H reaction converts glycerol to glycerol 3-phosphate. This reaction requires H,N- H,N H…arrow_forwardAfter adding a small amount of ATP labeled with radioactive phosphorus in the terminal position, [7-32P]ATP, to a yeast extract, a researcher finds about half of the 32P activity in P; within a few minutes, but the concentration of ATP remains unchanged. She then carries out the same experiment using ATP labeled with 32P in the central position, [ẞ-³2P]ATP, but the 32P does not appear in P; within such a short time. Which statements explain these results? Yeast cells reincorporate P; released from [ß-³2P]ATP into ATP more quickly than P¡ released from [y-³2P]ATP. Only the terminal (y) phosphorous atom acts as an electrophilic target for nucleophilic attack. The terminal (y) phosphoryl group undergoes a more rapid turnover than the central (B) phosphate group. Yeast cells maintain ATP levels by regulating the synthesis and breakdown of ATP. Correct Answerarrow_forwardCompare the structure of the nucleoside triphosphate CTP with the structure of ATP. NH₂ 0- 0- 0- ·P—O—P—O—P—O—CH₂ H H H H OH OH Cytidine triphosphate (CTP) Consider the reaction: ATP + CDP ADP + CTP NH 0- 0- 0- ¯0— P—O— P—O—P-O-CH₂ H Η о H H OH OH Adenosine triphosphate (ATP) NH₂ Now predict the approximate K'eq for this reaction. Now predict the approximate AG for this reaction. Narrow_forward
- The standard free energy, AGO, of hydrolysis of inorganic polyphosphate, polyP, is about −20 kJ/mol for each P; released. In a cell, it takes about 50 kJ/mol of energy to synthesize ATP from ADP and Pi. ○ P O Inorganic polyphosphate (polyP) Is it feasible for a cell to use polyP to synthesize ATP from ADP? Why or why not? No. The reaction is unidirectional and always proceeds in the direction of polyP synthesis from ATP. Yes. If [ADP] and [polyP] are kept high, and [ATP] is kept low, the actual free-energy change would be negative. No. The synthesis of ATP from ADP and P; has a large positive G'o compared to polyP hydrolysis. Yes. The hydrolysis of polyP has a sufficiently negative AG to overcome the positive AGO of ATP synthesis. Correct Answerarrow_forwardIn the glycolytic pathway, a six-carbon sugar (fructose 1,6-bisphosphate) is cleaved to form two three-carbon sugars, which undergo further metabolism. In this pathway, an isomerization of glucose 6-phosphate to fructose 6-phosphate (as shown in the diagram) occurs two steps before the cleavage reaction. The intervening step is phosphorylation of fructose 6-phosphate to fructose 1,6-bisphosphate. H H | H-C-OH H-C-OH C=0 HO-C-H HO-C-H phosphohexose isomerase H-C-OH H-C-OH H-C-OH H-C-OH CH₂OPO CH₂OPO Glucose 6-phosphate Fructose 6-phosphate What does the isomerization step accomplish from a chemical perspective? Isomerization alters the molecular formula of the compound, allowing for subsequent phosphorylation. Isomerization moves the carbonyl group, setting up a cleavage between the central carbons. Isomerization causes the gain of electrons, allowing for the eventual release of NADH. Isomerization reactions cause the direct production of energy in the form of ATP.arrow_forwardFrom data in the table, calculate the AG value for the reactions. Reaction AG' (kJ/mol) Phosphocreatine + H₂O →>> creatine + P -43.0 ADP + Pi → ATP + H₂O +30.5 Fructose +P → fructose 6-phosphate + H₂O +15.9 Phosphocreatine + ADP creatine + ATP AG'O ATP + fructose → ADP + fructose 6-phosphate AG'° kJ/mol kJ/molarrow_forward
- Macmillan Learning The phosphorylation of glucose to glucose 6-phosphate is the initial step in the catabolism of glucose. The direct phosphorylation of glucose by P, is described by the equation Glucose + P ← glucose 6-phosphate + H₂O AG = 13.8 kJ/mol Coupling ATP hydrolysis to glucose phosphorylation makes thermodynamic sense, but consider how the coupling might take place. Given that coupling requires a common intermediate, one conceivable mechanism is to use ATP hydrolysis to raise the intracellular concentration of Pi. The increase in P; concentration would drive the unfavorable phosphorylation of glucose by Pi- Is increasing the P; concentration a reasonable way to couple ATP hydrolysis and glucose phosphorylation? No. The phosphate salts of divalent cations would be present in excess and precipitate out. Yes. Increasing the concentration of P; would decrease K'eq and shift equilibrium to the right. Yes. The extra ATP hydrolysis would provide enough free energy to drive the…arrow_forwardThe phosphorylation of glucose to glucose 6-phosphate is the initial step in the catabolism of glucose. The direct phosphorylation of glucose by P, is described by the equation Glucose + P → glucose 6-phosphate + H₂O AG' = 13.8 kJ/mol In principle, at least, one way to increase the concentration of glucose 6-phosphate (G6P) is to drive the equilibrium reaction to the right by increasing the intracellular concentrations of glucose and Pj. The maximum solubility of glucose is less than 1 M, and the normal physiological concentration of G6P is 250 μM. Assume a fixed concentration of P, at 4.8 mM. The calculated value of K'cq is 4.74 × 10-³ M-¹. Calculate the intracellular concentration of glucose when the equilibrium concentration of glucose 6-phosphate is 250 μM, the normal physiological concentration. [glucose] = 10.99 Correct Answer Would increasing the concentration of glucose be a physiologically reasonable way to increase the concentration of G6P? No. Because the concentration of P,…arrow_forwardCalculate the equilibrium constant for the phosphorylation of glucose to glucose 6-phosphate at 37.0 °C. K'eq = M-' In the rat hepatocyte, the physiological concentrations of glucose and P, are maintained at approximately 4.8 mM. What is the equilibrium concentration of glucose 6-phosphate (G6P) obtained by the direct phosphorylation of glucose by P.? [G6P] = Does this reaction represent a reasonable metabolic step for the catabolism of glucose? Why or why not? Yes, because the value of AG" is positive. No, because the K'eq is too large for the reaction to proceed in the forward direction. Yes, because AG is negative at the calculated value of K'eq No, because [G6P] is likely to be higher than the calculated value. Marrow_forward
- The pKa values for glutamic acid are 2.19, 9.67, 4.25. Sketch out the titration curve for this amino acid and include all of the pKa values and the pl.arrow_forwardCalculate the isoelectronic point, pl, from the pKa values for histidine, arginine and asparagine.arrow_forwardThe free energy released by the hydrolysis of ATP under standard conditions is -30.5 kJ/mol. If ATP is hydrolyzed under standard conditions except at pH 5.0, is more or less free energy released? Why? More free energy is released because the increased [H+] stabilizes the negative charge on the ADP molecule. Less free energy is released because an acidic environment depletes cellular ATP levels. Less free energy is released because the reaction favors ATP production over hydrolysis due to the higher [H+] in solution. More free energy is released because the total cellular concentrations of ATP, ADP, and P; are greater at the lower pH. Correct Answerarrow_forward
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