PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Chapter 9.2, Problem 9.8P
Interpretation Introduction
Interpretation:
The balanced nuclear reaction for the beta emission of iodine-131 has to be given.
Concept Introduction:
Beta decay reaction:
Beta particles are electrons (electrons with negative electric charge). Beta decay occurs when a nucleus with too many protons or too many neutrons, one of the protons or neutrons is transformed into the other.
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Consider this step in a radical reaction:
Y
What type of step is this? Check all that apply.
Draw the products of the step on the right-hand side of the drawing area
below. If more than one set of products is possible, draw any set.
Also, draw the mechanism arrows on the left-hand side of the drawing
area to show how this happens.
ionization
propagation
initialization
passivation
none of the above
22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
trophilic aromatic substitution that shows the role of each group in stabilizing the
intermediate by further delocalizing its positive charge.
22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
Anisole
CH
(d)
Chapter 9 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
Ch. 9.1 - Prob. 9.1PCh. 9.1 - What is the difference between an particle and a...Ch. 9.1 - Prob. 9.3PCh. 9.1 - Identify Q in each of the following symbols. a....Ch. 9.2 - Prob. 9.5PCh. 9.2 - Prob. 9.6PCh. 9.2 - Prob. 9.7PCh. 9.2 - Prob. 9.8PCh. 9.2 - Prob. 9.9PCh. 9.2 - Prob. 9.10P
Ch. 9.2 - Prob. 9.11PCh. 9.3 - Prob. 9.13PCh. 9.3 - Prob. 9.14PCh. 9.3 - Prob. 9.15PCh. 9.3 - Prob. 9.16PCh. 9.4 - Prob. 9.17PCh. 9.4 - Prob. 9.18PCh. 9.5 - Prob. 9.19PCh. 9.5 - Prob. 9.20PCh. 9.6 - Prob. 9.21PCh. 9.6 - Prob. 9.22PCh. 9 - Compare fluorine-18 and fluorine-19 with regard to...Ch. 9 - Prob. 9.24UKCCh. 9 - Prob. 9.29UKCCh. 9 - Prob. 9.30UKCCh. 9 - Prob. 9.31APCh. 9 - Prob. 9.32APCh. 9 - Prob. 9.33APCh. 9 - Prob. 9.35APCh. 9 - Prob. 9.36APCh. 9 - Prob. 9.37APCh. 9 - Prob. 9.38APCh. 9 - Prob. 9.39APCh. 9 - Prob. 9.40APCh. 9 - Prob. 9.41APCh. 9 - Prob. 9.42APCh. 9 - Prob. 9.43APCh. 9 - Prob. 9.44APCh. 9 - Prob. 9.45APCh. 9 - Prob. 9.46APCh. 9 - Prob. 9.47APCh. 9 - Prob. 9.48APCh. 9 - Prob. 9.49APCh. 9 - Prob. 9.50APCh. 9 - Prob. 9.51APCh. 9 - Prob. 9.52APCh. 9 - Prob. 9.53APCh. 9 - Prob. 9.54APCh. 9 - Prob. 9.55APCh. 9 - Prob. 9.56APCh. 9 - Prob. 9.57APCh. 9 - Prob. 9.58APCh. 9 - Prob. 9.59APCh. 9 - Prob. 9.60APCh. 9 - Prob. 9.61APCh. 9 - Prob. 9.62APCh. 9 - Prob. 9.63APCh. 9 - Prob. 9.64APCh. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - Prob. 9.69APCh. 9 - Prob. 9.70APCh. 9 - Prob. 9.71APCh. 9 - Prob. 9.72APCh. 9 - Prob. 9.73APCh. 9 - Prob. 9.74APCh. 9 - Prob. 9.75APCh. 9 - Prob. 9.76APCh. 9 - Prob. 9.77APCh. 9 - Prob. 9.78APCh. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Prob. 9.81APCh. 9 - Prob. 9.82APCh. 9 - Prob. 9.83APCh. 9 - Prob. 9.84APCh. 9 - Prob. 9.85APCh. 9 - Prob. 9.86APCh. 9 - Prob. 9.87CPCh. 9 - Prob. 9.88CP
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- Show how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.arrow_forwardHelp me solve this problem. Thank you in advance.arrow_forward22.7 Predict the monoalkylated products of the following reactions with benzene. (a) AlCl3 Ya (b) AlCl3 (c) H3PO4 (d) 22.8 Think-Pair-Share AICI3 The reaction below is a common electrophilic aromatic substitution. SO3 H₂SO4 SO₂H (a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile. (b) Sketch the reaction coordinate diagram, where the product is lower in energy than the starting reactant. (c) Which step in the reaction mechanism is highest in energy? Explain. (d) Which of the following reaction conditions could be used in an electrophilic aro- matic substitution with benzene to provide substituted phenyl derivatives? (i) AICI3 HNO3 H₂SO4 K2Cr2O7 (iii) H₂SO4 (iv) H₂PO₁arrow_forward
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- V Consider this step in a radical reaction: Br: ? What type of step is this? Check all that apply. Draw the products of the step on the right-hand side of the drawing area below. If more than one set of products is possible, draw any set. Also, draw the mechanism arrows on the left-hand side of the drawing area to show how this happens. ⚫ionization termination initialization neutralization none of the abc Explanation Check 80 Ο F3 F1 F2 2 F4 01 % do5 $ 94 #3 X 5 C MacBook Air 25 F5 F6 66 ©2025 ˇ F7 29 & 7 8arrow_forwardShow how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.arrow_forwardno aiarrow_forward
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