PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Question
Chapter 9.6, Problem 9.22P
(a)
Interpretation Introduction
Interpretation:
The X in the following reaction has to be given.
The reaction is,
(b)
Interpretation Introduction
Interpretation:
The Y in the following reaction has to be given.
The reaction is,
(c)
Interpretation Introduction
Interpretation:
The Z in the following reaction has to be given.
The reaction is,
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Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
The rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.
Chapter 9 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
Ch. 9.1 - Prob. 9.1PCh. 9.1 - What is the difference between an particle and a...Ch. 9.1 - Prob. 9.3PCh. 9.1 - Identify Q in each of the following symbols. a....Ch. 9.2 - Prob. 9.5PCh. 9.2 - Prob. 9.6PCh. 9.2 - Prob. 9.7PCh. 9.2 - Prob. 9.8PCh. 9.2 - Prob. 9.9PCh. 9.2 - Prob. 9.10P
Ch. 9.2 - Prob. 9.11PCh. 9.3 - Prob. 9.13PCh. 9.3 - Prob. 9.14PCh. 9.3 - Prob. 9.15PCh. 9.3 - Prob. 9.16PCh. 9.4 - Prob. 9.17PCh. 9.4 - Prob. 9.18PCh. 9.5 - Prob. 9.19PCh. 9.5 - Prob. 9.20PCh. 9.6 - Prob. 9.21PCh. 9.6 - Prob. 9.22PCh. 9 - Compare fluorine-18 and fluorine-19 with regard to...Ch. 9 - Prob. 9.24UKCCh. 9 - Prob. 9.29UKCCh. 9 - Prob. 9.30UKCCh. 9 - Prob. 9.31APCh. 9 - Prob. 9.32APCh. 9 - Prob. 9.33APCh. 9 - Prob. 9.35APCh. 9 - Prob. 9.36APCh. 9 - Prob. 9.37APCh. 9 - Prob. 9.38APCh. 9 - Prob. 9.39APCh. 9 - Prob. 9.40APCh. 9 - Prob. 9.41APCh. 9 - Prob. 9.42APCh. 9 - Prob. 9.43APCh. 9 - Prob. 9.44APCh. 9 - Prob. 9.45APCh. 9 - Prob. 9.46APCh. 9 - Prob. 9.47APCh. 9 - Prob. 9.48APCh. 9 - Prob. 9.49APCh. 9 - Prob. 9.50APCh. 9 - Prob. 9.51APCh. 9 - Prob. 9.52APCh. 9 - Prob. 9.53APCh. 9 - Prob. 9.54APCh. 9 - Prob. 9.55APCh. 9 - Prob. 9.56APCh. 9 - Prob. 9.57APCh. 9 - Prob. 9.58APCh. 9 - Prob. 9.59APCh. 9 - Prob. 9.60APCh. 9 - Prob. 9.61APCh. 9 - Prob. 9.62APCh. 9 - Prob. 9.63APCh. 9 - Prob. 9.64APCh. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - Prob. 9.69APCh. 9 - Prob. 9.70APCh. 9 - Prob. 9.71APCh. 9 - Prob. 9.72APCh. 9 - Prob. 9.73APCh. 9 - Prob. 9.74APCh. 9 - Prob. 9.75APCh. 9 - Prob. 9.76APCh. 9 - Prob. 9.77APCh. 9 - Prob. 9.78APCh. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Prob. 9.81APCh. 9 - Prob. 9.82APCh. 9 - Prob. 9.83APCh. 9 - Prob. 9.84APCh. 9 - Prob. 9.85APCh. 9 - Prob. 9.86APCh. 9 - Prob. 9.87CPCh. 9 - Prob. 9.88CP
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