9.99 The chemical reaction BBr 3 ( g ) + BCl 3 ( g ) → BBr 2 Cl ( g ) + BCl 2 Br ( g ) , has an enthalpy change very close to zero. Using Lewis structures of the molecules, all of which have a central boron atom, provide a molecular-level description of why Δ H ° for this reaction might be very small.
9.99 The chemical reaction BBr 3 ( g ) + BCl 3 ( g ) → BBr 2 Cl ( g ) + BCl 2 Br ( g ) , has an enthalpy change very close to zero. Using Lewis structures of the molecules, all of which have a central boron atom, provide a molecular-level description of why Δ H ° for this reaction might be very small.
Solution Summary: The author explains the reason for the small change in the enthalpy of the reaction given below.
9.99 The chemical reaction
BBr
3
(
g
)
+
BCl
3
(
g
)
→
BBr
2
Cl
(
g
)
+
BCl
2
Br
(
g
)
, has an enthalpy change very close to zero. Using Lewis structures of the molecules, all of which have a central boron atom, provide a molecular-level description of why
Δ
H
°
for this reaction might be very small.
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression:
AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T
A. Calculate the value of AS for the process.
B. Next, use the Gibbs-Helmholtz equation:
(a(AG/T))
ΔΗ
-
T2
to calculate the value of AH for the process.
None
Chapter 9 Solutions
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