The graph which shows how the concentration of the reactant and products of a reversible reaction varies with time has to be sketched. Concept Introduction: Reversible reaction: Reversible reaction is a chemical reaction in which the convertion of reactants to products(forward reaction) and the conversion of products to reactants(reverse raction) happens simultaneously. Example: Consider the reaction, H 2 + I 2 ⇌ 2HI The above recation repreasents a reversible reaction. The double headed arrow is used to represent the reversible reaction. Forward reaction is: H 2 + I 2 → 2HI Backward reaction is: 2HI → H 2 + I 2 Both the forward and backward reaction occurs simultaneously.
The graph which shows how the concentration of the reactant and products of a reversible reaction varies with time has to be sketched. Concept Introduction: Reversible reaction: Reversible reaction is a chemical reaction in which the convertion of reactants to products(forward reaction) and the conversion of products to reactants(reverse raction) happens simultaneously. Example: Consider the reaction, H 2 + I 2 ⇌ 2HI The above recation repreasents a reversible reaction. The double headed arrow is used to represent the reversible reaction. Forward reaction is: H 2 + I 2 → 2HI Backward reaction is: 2HI → H 2 + I 2 Both the forward and backward reaction occurs simultaneously.
Solution Summary: The author explains that the graph shows how the concentration of reactants and products of a reversible reaction varies with time.
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
Chapter 9, Problem 9.65EP
Interpretation Introduction
Interpretation:
The graph which shows how the concentration of the reactant and products of a reversible reaction varies with time has to be sketched.
Concept Introduction:
Reversible reaction:
Reversible reaction is a chemical reaction in which the convertion of reactants to products(forward reaction) and the conversion of products to reactants(reverse raction) happens simultaneously.
Example:
Consider the reaction,
H2+ I2⇌ 2HI
The above recation repreasents a reversible reaction. The double headed arrow is used to represent the reversible reaction.
Forward reaction is:
H2 + I2→ 2HI
Backward reaction is:
2HI → H2+ I2
Both the forward and backward reaction occurs simultaneously.
Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 9 Solutions
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