When boron-10 is used in control rods for nuclear reactor it absorbs one neutron and then emits an alpha particle. This reaction should be written with all the product nuclides. Concept Introduction: Total mass number of all nuclides in reactant side must be equal to the total mass number of all nuclides in product side. Similarly total atomic number of all nuclides in reactant side must be equal to the total atomic number of all nuclides in product side.

Question

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

Answer 1

Question

Chapter 9, Problem 9.59P

Interpretation Introduction

Interpretation:

When boron-10 is used in control rods for nuclear reactor it absorbs one neutron and then emits an alpha particle. This reaction should be written with all the product nuclides.

Concept Introduction:

Total mass number of all nuclides in reactant side must be equal to the total mass number of all nuclides in product side.

Similarly total atomic number of all nuclides in reactant side must be equal to the total atomic number of all nuclides in product side.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

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