Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 9, Problem 9.1P
Interpretation Introduction

Interpretation:

A coefficient of performance ∅ for a heat pump and ∅for a Carnot heat pump should be defined.

Concept Introduction:

  Thermal efficiency = Work out / Work in

  COP = What we want / What we pay

Expert Solution & Answer
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Answer to Problem 9.1P

Coefficient of performance of Carnot heat pump is greater than unity.

Given Information:

Measure of performance is defined as what you get compared to what you pay for. So, for an engine, the thermal efficiency is η = |W|/ |QH| while for a refrigerator, the coefficient of performance is ω = |QH|/ |W|.

Explanation:

  Thermal efficiency = Work out / Work in           = Benefit / CostCarnot heat engineQH= W + QCW = QH QCEfficiency (e) = WQH             = QH QCQH= 1  QCQH= 1  TcTH

Efficiency of refrigerator and heat pump is given by coefficient of performance (COP).

  COP = What we want / What we payCOP = QC( We want heat to escape)W QH= W + QCSo, COP = QH W W × (1 Q H 1 Q H )      after multiply & divide by 1/QH           = 1W Q H W Q H COP = 1- ee           since e =W/QH

Heat pump

  COP = What we want / What we pay           =QHW (we want heat to enter)COP =QHW         Hence, COP > 1

Carnot pump is a Carnot engine that is driven backward by another engine. It removes heat from cold reservoir and exhaust heat into hot reservoir.

Here, coefficient of performance is equal to reciprocal of Carnot efficiency.

This figure is reverse of Carnot heat engine

  q`4=  q1q`2=  q3 e` =q`4W`=  q1 q`2+ q`4=q1q1 q4e` = 11 q 3 q 1         Carnot heat engine=1 1 Q c Q H e'=1e                    

COP of Carnot heat pump is greater than unity.

Carnot cycle is a speculative thermodynamic process which offers a ceiling limit on the efficacy that any conventional thermodynamic system can acquire while converting energy to work or on the other hand, the efficacy of a refrigerating system in generating a difference in temperature by applying work to the system.

Explanation of Solution

Given Information:

Measure of performance is defined as what you get compared to what you pay for. So, for an engine, the thermal efficiency is η = |W|/ |QH| while for a refrigerator, the coefficient of performance is ω = |QH|/ |W|.

  Thermal efficiency = Work out / Work in           = Benefit / CostCarnot heat engineQH= W + QCW = QH QCEfficiency (e) = WQH             = QH QCQH= 1  QCQH= 1  TcTH

Efficiency of refrigerator and heat pump is given by coefficient of performance (COP).

  COP = What we want / What we payCOP = QC( We want heat to escape)W QH= W + QCSo, COP = QH W W × (1 Q H 1 Q H )      after multiply & divide by 1/QH           = 1W Q H W Q H COP = 1- ee           since e =W/QH

Heat pump

  COP = What we want / What we pay           =QHW (we want heat to enter)COP =QHW         Hence, COP > 1

Carnot pump is a Carnot engine that is driven backward by another engine. It removes heat from cold reservoir and exhaust heat into hot reservoir.

Here, coefficient of performance is equal to reciprocal of Carnot efficiency.

This figure is reverse of Carnot heat engine

  q`4=  q1q`2=  q3 e` =q`4W`=  q1 q`2+ q`4=q1q1 q4e` = 11 q 3 q 1         Carnot heat engine=1 1 Q c Q H e'=1e                    

COP of Carnot heat pump is greater than unity.

Conclusion

Carnot cycle is a speculative thermodynamic process which offers a ceiling limit on the efficacy that any conventional thermodynamic system can acquire while converting energy to work or on the other hand, the efficacy of a refrigerating system in generating a difference in temperature by applying work to the system.

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