Chemistry
4th Edition
ISBN: 9780393919370
Author: Thomas R. Gilbert
Publisher: NORTON
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Chapter 9, Problem 9.18QP
Interpretation Introduction
Interpretation: The given molecular geometries are to be arranged in the order of increasing bond angle.
Concept introduction: The angle between the atoms bonded to central atom is known as bond angle. The bond angle varies with the change in molecular geometry.
To determine: The given molecular geometries in the increasing order of their bond angles.
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Draw the anti-Markovnikov product of the hydration of this alkene.
this problem.
Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 9 Solutions
Chemistry
Ch. 9.2 - Prob. 1PECh. 9.2 - Prob. 2PECh. 9.2 - Prob. 3PECh. 9.3 - Prob. 4PECh. 9.4 - Prob. 5PECh. 9.4 - Prob. 6PECh. 9.4 - Prob. 7PECh. 9.5 - Prob. 8PECh. 9.7 - Prob. 9PECh. 9.7 - Prob. 10PE
Ch. 9 - Prob. 9.1VPCh. 9 - Prob. 9.2VPCh. 9 - Prob. 9.3VPCh. 9 - Prob. 9.4VPCh. 9 - Prob. 9.5VPCh. 9 - Prob. 9.6VPCh. 9 - Prob. 9.7VPCh. 9 - Prob. 9.8VPCh. 9 - Prob. 9.9QPCh. 9 - Prob. 9.10QPCh. 9 - Prob. 9.11QPCh. 9 - Prob. 9.12QPCh. 9 - Prob. 9.13QPCh. 9 - Prob. 9.14QPCh. 9 - Prob. 9.15QPCh. 9 - Prob. 9.16QPCh. 9 - Prob. 9.17QPCh. 9 - Prob. 9.18QPCh. 9 - Prob. 9.19QPCh. 9 - Prob. 9.20QPCh. 9 - Prob. 9.21QPCh. 9 - Prob. 9.22QPCh. 9 - Prob. 9.23QPCh. 9 - Prob. 9.24QPCh. 9 - Prob. 9.25QPCh. 9 - Prob. 9.26QPCh. 9 - Prob. 9.27QPCh. 9 - Prob. 9.28QPCh. 9 - Prob. 9.29QPCh. 9 - Prob. 9.30QPCh. 9 - Prob. 9.31QPCh. 9 - Prob. 9.32QPCh. 9 - Prob. 9.33QPCh. 9 - Prob. 9.34QPCh. 9 - Prob. 9.35QPCh. 9 - Prob. 9.36QPCh. 9 - Prob. 9.37QPCh. 9 - Prob. 9.38QPCh. 9 - Prob. 9.39QPCh. 9 - Prob. 9.40QPCh. 9 - Prob. 9.41QPCh. 9 - Prob. 9.42QPCh. 9 - Prob. 9.43QPCh. 9 - Prob. 9.44QPCh. 9 - Prob. 9.45QPCh. 9 - Prob. 9.46QPCh. 9 - Prob. 9.47QPCh. 9 - Prob. 9.48QPCh. 9 - Prob. 9.49QPCh. 9 - Prob. 9.50QPCh. 9 - Prob. 9.51QPCh. 9 - Prob. 9.52QPCh. 9 - Prob. 9.53QPCh. 9 - Prob. 9.54QPCh. 9 - Prob. 9.55QPCh. 9 - Prob. 9.56QPCh. 9 - Prob. 9.57QPCh. 9 - Prob. 9.58QPCh. 9 - Prob. 9.59QPCh. 9 - Prob. 9.60QPCh. 9 - Prob. 9.61QPCh. 9 - Prob. 9.62QPCh. 9 - Prob. 9.63QPCh. 9 - Prob. 9.64QPCh. 9 - Prob. 9.65QPCh. 9 - Prob. 9.66QPCh. 9 - Prob. 9.67QPCh. 9 - Prob. 9.68QPCh. 9 - Prob. 9.69QPCh. 9 - Prob. 9.70QPCh. 9 - Prob. 9.71QPCh. 9 - Prob. 9.72QPCh. 9 - Prob. 9.73QPCh. 9 - Prob. 9.74QPCh. 9 - Prob. 9.75QPCh. 9 - Prob. 9.76QPCh. 9 - Prob. 9.77QPCh. 9 - Prob. 9.78QPCh. 9 - Prob. 9.79QPCh. 9 - Prob. 9.80QPCh. 9 - Prob. 9.81QPCh. 9 - Prob. 9.82QPCh. 9 - Prob. 9.83QPCh. 9 - Prob. 9.84QPCh. 9 - Prob. 9.85QPCh. 9 - Prob. 9.86QPCh. 9 - Prob. 9.87QPCh. 9 - Prob. 9.88QPCh. 9 - Prob. 9.89QPCh. 9 - Prob. 9.90QPCh. 9 - Prob. 9.91QPCh. 9 - Prob. 9.92QPCh. 9 - Prob. 9.93QPCh. 9 - Prob. 9.94QPCh. 9 - Prob. 9.95QPCh. 9 - Prob. 9.96QPCh. 9 - Prob. 9.97QPCh. 9 - Prob. 9.98QPCh. 9 - Prob. 9.99QPCh. 9 - Prob. 9.100QPCh. 9 - Prob. 9.101APCh. 9 - Prob. 9.102APCh. 9 - Prob. 9.103APCh. 9 - Prob. 9.104APCh. 9 - Prob. 9.105APCh. 9 - Prob. 9.106APCh. 9 - Prob. 9.107APCh. 9 - Prob. 9.108APCh. 9 - Prob. 9.109APCh. 9 - Prob. 9.110APCh. 9 - Prob. 9.111APCh. 9 - Prob. 9.112APCh. 9 - Prob. 9.113APCh. 9 - Prob. 9.114APCh. 9 - Prob. 9.115APCh. 9 - Prob. 9.116APCh. 9 - Prob. 9.117APCh. 9 - Prob. 9.118APCh. 9 - Prob. 9.119APCh. 9 - Prob. 9.120APCh. 9 - Prob. 9.121APCh. 9 - Prob. 9.122APCh. 9 - Prob. 9.123APCh. 9 - Prob. 9.124APCh. 9 - Prob. 9.125APCh. 9 - Prob. 9.126APCh. 9 - Prob. 9.127APCh. 9 - Prob. 9.128AP
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