Chemistry: The Molecular Nature of Matter and Change - Standalone book
Chemistry: The Molecular Nature of Matter and Change - Standalone book
7th Edition
ISBN: 9780073511177
Author: Martin Silberberg Dr., Patricia Amateis Professor
Publisher: McGraw-Hill Education
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Chapter 9, Problem 9.17P

(a)

Interpretation Introduction

Interpretation:

The dependence of lattice energy of an ionic compound on the charges and sizes of the ions is to be determined.

Concept introduction:

Lattice energy is the amount of energy released when the ions combine to form an ionic compound. It is determined to measure the strength of the ionic interactions present in the lattice. A high negative value of lattice energy is the reason behind the formation of ionic compounds.

The lattice energy of compounds depends upon generally three factors as follows:

1. Ionic Size

2. Ionic Charge

3. Arrangement of ions in the lattice

(b)

Interpretation Introduction

Interpretation:

The given ionic arrangement of three general salts is to be ranked in increasing order of lattice energy.

Concept introduction:

Lattice energy is the amount of energy released when the ions combine to form an ionic compound. It is determined to measure the strength of the ionic interactions present in the lattice. A high negative value of lattice energy is the reason behind the formation of ionic compounds.

The lattice energy of compounds depends upon generally three factors as follows:

1. Ionic Size

2. Ionic Charge

3. Arrangement of ions in the lattice

Lattice energy depends upon the ionic interaction between the ions present in the lattice. Therefore, lattice energy decreases with the increase in ionic size and decrease in the ionic charge. The value of lattice energy also depends upon the arrangement of ions. More will be the ions in the lattice higher will be the value of lattice energy.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+
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Chapter 9 Solutions

Chemistry: The Molecular Nature of Matter and Change - Standalone book

Ch. 9.5 - Arrange each set of bonds in order of increasing...Ch. 9.5 - Prob. 9.5BFPCh. 9 - Prob. 9.1PCh. 9 - Prob. 9.2PCh. 9 - What is the relationship between the tendency of a...Ch. 9 - Prob. 9.4PCh. 9 - Prob. 9.5PCh. 9 - State the type of bonding—ionic, covalent, or...Ch. 9 - State the type of bonding—ionic, covalent, or...Ch. 9 - State the type of bonding—ionic, covalent, or...Ch. 9 - Prob. 9.9PCh. 9 - Prob. 9.10PCh. 9 - Prob. 9.11PCh. 9 - Prob. 9.12PCh. 9 - Prob. 9.13PCh. 9 - Give the group number and condensed electron...Ch. 9 - Give the group number and condensed electron...Ch. 9 - Prob. 9.16PCh. 9 - Prob. 9.17PCh. 9 - Prob. 9.18PCh. 9 - Prob. 9.19PCh. 9 - Prob. 9.20PCh. 9 - Prob. 9.21PCh. 9 - Prob. 9.22PCh. 9 - Prob. 9.23PCh. 9 - Prob. 9.24PCh. 9 - Prob. 9.25PCh. 9 - For each pair, choose the compound with the larger...Ch. 9 - Prob. 9.27PCh. 9 - For each pair, choose the compound with the...Ch. 9 - Prob. 9.29PCh. 9 - Use the following to calculate of NaCl: Compared...Ch. 9 - Use the following to calculate of MgF2: Compared...Ch. 9 - Prob. 9.32PCh. 9 - Born-Haber cycles were used to obtain the first...Ch. 9 - Prob. 9.34PCh. 9 - Prob. 9.35PCh. 9 - Prob. 9.36PCh. 9 - How does the energy of the bond between a given...Ch. 9 - When liquid benzene (C6H6) boils, does the gas...Ch. 9 - Prob. 9.39PCh. 9 - Prob. 9.40PCh. 9 - Prob. 9.41PCh. 9 - Prob. 9.42PCh. 9 - The text points out that, for similar types of...Ch. 9 - Why is there a discrepancy between an enthalpy of...Ch. 9 - Which of the following gases would you expect to...Ch. 9 - Which of the following gases would you expect to...Ch. 9 - Use bond energies to calculate the enthalpy of...Ch. 9 - Prob. 9.48PCh. 9 - Prob. 9.49PCh. 9 - Prob. 9.50PCh. 9 - Prob. 9.51PCh. 9 - What is the general relationship between IE1 and...Ch. 9 - Is the H—O bond in water nonpolar covalent, polar...Ch. 9 - Prob. 9.54PCh. 9 - How is the partial ionic character of a bond in a...Ch. 9 - Using the periodic table only, arrange the...Ch. 9 - Prob. 9.57PCh. 9 - Prob. 9.58PCh. 9 - Prob. 9.59PCh. 9 - Prob. 9.60PCh. 9 - Use Figure 9.21 to indicate the polarity of each...Ch. 9 - Prob. 9.62PCh. 9 - Prob. 9.63PCh. 9 - Prob. 9.64PCh. 9 - Prob. 9.65PCh. 9 - Prob. 9.66PCh. 9 - Prob. 9.67PCh. 9 - Prob. 9.68PCh. 9 - Prob. 9.69PCh. 9 - Prob. 9.70PCh. 9 - Prob. 9.71PCh. 9 - Geologists have a rule of thumb: when molten rock...Ch. 9 - Prob. 9.73PCh. 9 - Use Lewis electron-dot symbols to represent the...Ch. 9 - Prob. 9.75PCh. 9 - Prob. 9.76PCh. 9 - By using photons of specific wavelengths, chemists...Ch. 9 - Prob. 9.78PCh. 9 - Prob. 9.79PCh. 9 - Prob. 9.80PCh. 9 - Prob. 9.81PCh. 9 - Prob. 9.82PCh. 9 - Prob. 9.83PCh. 9 - Find the longest wavelengths of light that can...Ch. 9 - The work function (ϕ) of a metal is the minimum...Ch. 9 - Prob. 9.86PCh. 9 - Prob. 9.87PCh. 9 - Prob. 9.88PCh. 9 - In a future hydrogen-fuel economy, the cheapest...Ch. 9 - Prob. 9.90PCh. 9 - Prob. 9.91P
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