
Chemistry
7th Edition
ISBN: 9780321940872
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Question
Chapter 9, Problem 9.101SP
Interpretation Introduction
To determine:
The balanced combustion reaction and amount of energy released in kJ/mL
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show the retrosynthesis of this
molecule step by step starting with
1,3-dimethoxy benzene
H3CO
OH
OH
OCH 3
Consider the reaction of a propanoate ester with hydroxide ion shown below. A
series of four alcohol leaving groups were tested to determine which would be the
best leaving group.
Based on the pKa values of the alcohols, predict which alcohol would produce the
fastest hydrolysis reaction.
HO
FOR
A
Alcohol I, pKa =16.0
B
Alcohol II, pKa =10.0
C
Alcohol III, pKa = 7.2
+ ROH
D
Alcohol IV, pKa = 6.6
Chapter 9 Solutions
Chemistry
Ch. 9 - Prob. 9.1PCh. 9 - Conceptual APPLY 9.2 How much work is done in...Ch. 9 - PRACTICE 9.3 The reaction between hydrogen and...Ch. 9 - Conceptual APPLY 9.4 The following reaction has E...Ch. 9 - PRACTICE 9.5 Use the following t her mo chemical...Ch. 9 - APPLY 9.6 Approximately, 1.8106 kJ of energy is...Ch. 9 - PRACTICE 9.7 Indicate the direction of heat...Ch. 9 - APPLY 9.8 Instant hot packs and cold packs contain...Ch. 9 - PRACTICE 9.9 What is the specific heat of lead in...Ch. 9 - APPLY 9.10 Calculate the heat capacity (C) of a...
Ch. 9 - PRACTICE 9.11 When 25.0 mL of 1.0 M H2SO4 is added...Ch. 9 - Prob. 9.12ACh. 9 - Prob. 9.13PCh. 9 - Prob. 9.14ACh. 9 - Prob. 9.15PCh. 9 - Prob. 9.16ACh. 9 - Prob. 9.17PCh. 9 - APPLY 9.18 Benzene (C6H6) has two resonance...Ch. 9 - Prob. 9.19PCh. 9 - Prob. 9.20ACh. 9 - Prob. 9.21PCh. 9 - Prob. 9.22ACh. 9 - Prob. 9.23PCh. 9 - Prob. 9.24ACh. 9 - Prob. 9.25PCh. 9 - Prob. 9.26PCh. 9 - Prob. 9.27PCh. 9 - Prob. 9.28PCh. 9 - Prob. 9.29PCh. 9 - A piece of dry ice (solid CO2) is placed inside a...Ch. 9 - Imagine a reaction that results in a change in...Ch. 9 - 9.32 Redraw the following diagram to represent the...Ch. 9 - 9.33 A reaction is carried out in a cylinder...Ch. 9 - Prob. 9.34CPCh. 9 - Prob. 9.35CPCh. 9 - Prob. 9.36CPCh. 9 - Prob. 9.37CPCh. 9 - Prob. 9.38CPCh. 9 - Prob. 9.39CPCh. 9 - What is the difference between heat and...Ch. 9 - What is internal energy?Ch. 9 - Prob. 9.42SPCh. 9 - Prob. 9.43SPCh. 9 - Which of the following are state functions, and...Ch. 9 - Prob. 9.45SPCh. 9 - Calculate the work done in joules by a chemical...Ch. 9 - The addition of H2 to C=C double bonds is an...Ch. 9 - Prob. 9.48SPCh. 9 - Prob. 9.49SPCh. 9 - 9.50 A reaction inside a cylindrical container...Ch. 9 - At a constant pressure of 0.905 atm, a chemical...Ch. 9 - Prob. 9.52SPCh. 9 - Prob. 9.53SPCh. 9 - Prob. 9.54SPCh. 9 - Prob. 9.55SPCh. 9 - 9.56 The explosion of 2.00 mol of solid...Ch. 9 - Prob. 9.57SPCh. 9 - Prob. 9.58SPCh. 9 - Assume that a particular reaction evolves 244 kJ...Ch. 9 - Prob. 9.60SPCh. 9 - A reaction takes place at a constant pressure of...Ch. 9 - Prob. 9.62SPCh. 9 - Indicate the direction of heat transfer between...Ch. 9 - Prob. 9.64SPCh. 9 - Prob. 9.65SPCh. 9 - Aluminum metal reacts with chlorine with a...Ch. 9 - Prob. 9.67SPCh. 9 - 9,68 How much heat in kilojoules is evolved or...Ch. 9 - 9.69 Nitromethane (CH3NO2), sometimes used as a...Ch. 9 - How much heat in kilojoules is evolved or absorbed...Ch. 9 - How much heat in kilojoules is evolved or absorbed...Ch. 9 - What is the difference between heat capacity and...Ch. 9 - Does a measurement carried out in a bomb...Ch. 9 - Sodium metal is sometimes used as a cooling agent...Ch. 9 - Titanium metal is used as a structural material in...Ch. 9 - Assuming that Coca Cola has the same specific heat...Ch. 9 - Calculate the amount of heat required to raise the...Ch. 9 - Instant cold packs used to treat athletic injuries...Ch. 9 - 9.79 Instant hot packs contain a solid and a pouch...Ch. 9 - Prob. 9.80SPCh. 9 - Prob. 9.81SPCh. 9 - 9.82 When 0.187 g of benzene, C6H6 is burned in a...Ch. 9 - Prob. 9.83SPCh. 9 - 9.84 How is the standard state of an element...Ch. 9 - Prob. 9.85SPCh. 9 - Prob. 9.86SPCh. 9 - Prob. 9.87SPCh. 9 - Prob. 9.88SPCh. 9 - Prob. 9.89SPCh. 9 - Prob. 9.90SPCh. 9 - Prob. 9.91SPCh. 9 - Write balanced equations for the formation of the...Ch. 9 - Prob. 9.93SPCh. 9 - Prob. 9.94SPCh. 9 - Prob. 9.95SPCh. 9 - Prob. 9.96SPCh. 9 - Prob. 9.97SPCh. 9 - Prob. 9.98SPCh. 9 - Prob. 9.99SPCh. 9 - Prob. 9.100SPCh. 9 - Prob. 9.101SPCh. 9 - Prob. 9.102SPCh. 9 - Prob. 9.103SPCh. 9 - Prob. 9.104SPCh. 9 - Prob. 9.105SPCh. 9 - Prob. 9.106SPCh. 9 - Prob. 9.107SPCh. 9 - Use the average bond dissociation energies in...Ch. 9 - 9.109 Use the bond dissociation energies in Table...Ch. 9 - Prob. 9.110SPCh. 9 - Calculate an approximate heat of combustion for...Ch. 9 - Prob. 9.112SPCh. 9 - Prob. 9.113SPCh. 9 - Prob. 9.114SPCh. 9 - Prob. 9.115SPCh. 9 - Prob. 9.116SPCh. 9 - Prob. 9.117SPCh. 9 - Prob. 9.118SPCh. 9 - Prob. 9.119SPCh. 9 - One of the steps in the cracking of petroleum into...Ch. 9 - The commercial production of 1,2-dichloro ethane,...Ch. 9 - Prob. 9.122SPCh. 9 - Prob. 9.123SPCh. 9 - Suppose that a reaction has H = -33 kJ and S = -58...Ch. 9 - Suppose that a reaction has H = +41 kJ and S =...Ch. 9 - Prob. 9.126SPCh. 9 - Vinyl chloride (H2C=CHCl), the starting material...Ch. 9 - Ethyl alcohol has Hfusion = 5.02 kJ/mol and melts...Ch. 9 - Chloroform has Hvaporization = 29.2 kJ/mol and...Ch. 9 - When a sample of a hydrocarbon fuel is ignited and...Ch. 9 - Used in welding metals, the reaction of acetylene...Ch. 9 - Ethyl chloride (C2H5Cl), a substance used as a...Ch. 9 - When 1.50 g of magnesium metal is allowed to react...Ch. 9 - Prob. 9.134CPCh. 9 - Find H in kilojoules for the reaction of nitric...Ch. 9 - The boiling point of a substance is defined as the...Ch. 9 - Prob. 9.137CPCh. 9 - Prob. 9.138CPCh. 9 - Prob. 9.139CPCh. 9 - Isooctane, C8H18, is the component of gasoline...Ch. 9 - We said in Section 9.1 that the potential energy...Ch. 9 - For a process to be spontaneous, the total entropy...Ch. 9 - Set up a Hess's law cycle, and use the following...Ch. 9 - A 110.0 g piece of molybdenum metal is heated to...Ch. 9 - Given 400.0 g of hot tea at 80.0 °C, what mass of...Ch. 9 - Citric acid has three dissociable hydrogens. When...Ch. 9 - Assume that 100.0 mL of 0.200 M CsOH and 50.0 mL...Ch. 9 - Imagine that you dissolve 10.0 g of a mixture of...Ch. 9 - Consider the reaction: 4CO(g)+2NO2(g)4CO2(g)+N2(g)...Ch. 9 - The reaction S8(g)4S2(g) has H = +237 kJ (a) The...Ch. 9 - Prob. 9.151MPCh. 9 - Prob. 9.152MPCh. 9 - (a) Write a balanced equation for the reaction of...Ch. 9 - Prob. 9.154MPCh. 9 - Prob. 9.155MP
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