PRINCIPLES+REACTIONS
8th Edition
ISBN: 9781337759632
Author: Masterton
Publisher: CENGAGE L
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Textbook Question
Chapter 9, Problem 75QAP
The following data are given for CC14:
How much heat is required to vaporize 20.0 L of CCl4 at its normal boiling point?
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Chapter 9 Solutions
PRINCIPLES+REACTIONS
Ch. 9 - Prob. 1QAPCh. 9 - Prob. 2QAPCh. 9 - The vapor pressure of I2(s) at 30C is 0.466 mm Hg....Ch. 9 - Prob. 4QAPCh. 9 - Trichloroethane, C2H3Cl3 is used as a degreaser...Ch. 9 - p-Dichlorobenzene, C6H4Cl2, can be one of the...Ch. 9 - Prob. 7QAPCh. 9 - Dichloromethane, CH2Cl2,is widely used as a...Ch. 9 - Prob. 9QAPCh. 9 - Prob. 10QAP
Ch. 9 - At a resort in Sante Fe, New Mexico, the...Ch. 9 - Prob. 12QAPCh. 9 - Prob. 13QAPCh. 9 - Consider the following data for the vapor pressure...Ch. 9 - Referring to Figure 9.7, state what phase(s)...Ch. 9 - Referring to Figure 9.7, state what phase(s) is...Ch. 9 - Prob. 17QAPCh. 9 - Consider the phase diagram of the compound in...Ch. 9 - Prob. 19QAPCh. 9 - Prob. 20QAPCh. 9 - Given the following data about xenon,...Ch. 9 - Given the following data about CO2: • triple...Ch. 9 - A pure substance X has the following properties:...Ch. 9 - Prob. 24QAPCh. 9 - Prob. 25QAPCh. 9 - Arrange the following compounds in order of...Ch. 9 - Which of the following would you expect to show...Ch. 9 - Which of the following compounds would you expect...Ch. 9 - Prob. 29QAPCh. 9 - Prob. 30QAPCh. 9 - Explain in terms of forces between structural...Ch. 9 - Prob. 32QAPCh. 9 - Prob. 33QAPCh. 9 - In which of the following processes is it...Ch. 9 - For each of the following pairs, choose the member...Ch. 9 - Follow the directions for Question 35 for the...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - Prob. 39QAPCh. 9 - Prob. 40QAPCh. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Prob. 43QAPCh. 9 - Prob. 44QAPCh. 9 - Give the formula of a solid containing Si that is...Ch. 9 - Prob. 46QAPCh. 9 - Prob. 47QAPCh. 9 - Describe the structural units in (a) C (graphite)...Ch. 9 - Molybdenum has an atomic radius of 0.145 nm. The...Ch. 9 - Nickel has an atomic radius of 0.162 nm. The edge...Ch. 9 - Lead (atomicradius=0.181nm) crystallizes with a...Ch. 9 - Iridium crystallizes in a face-centered unit cell....Ch. 9 - In the LiCl structure shown in Figure 9.21, the...Ch. 9 - Potassium iodide has a unit cell similar to that...Ch. 9 - Prob. 55QAPCh. 9 - Consider the CsCl cell (Figure 9.21). The ionic...Ch. 9 - Consider the sodium chloride unit cell shown in...Ch. 9 - Consider the CsCl unit shown in Figure 9.21. How...Ch. 9 - A 1.25-L clean and dry flask is sealed. The air in...Ch. 9 - Aluminum metal crystallizes with a face-centered...Ch. 9 - Consider a sealed flask with a movable piston that...Ch. 9 - Prob. 62QAPCh. 9 - Prob. 63QAPCh. 9 - Prob. 64QAPCh. 9 - Chloroform, CHCl3, has a normal boiling point of...Ch. 9 - Prob. 66QAPCh. 9 - Prob. 67QAPCh. 9 - In the blanks provided, answer the questions...Ch. 9 - Answer the questions below, by filling in the...Ch. 9 - Prob. 70QAPCh. 9 - Prob. 71QAPCh. 9 - What is the difference between (a) a covalent bond...Ch. 9 - Four shiny solids are labeled A, B, C, and D....Ch. 9 - Prob. 74QAPCh. 9 - The following data are given for CC14:...Ch. 9 - Iron crystallizes in a body-centered unit cell....Ch. 9 - Prob. 77QAPCh. 9 - Trichloroethane, C2H3Cl3, is the active ingredient...Ch. 9 - Prob. 79QAPCh. 9 - Prob. 80QAPCh. 9 - Prob. 81QAP
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- Explain why 15 g of steam at 100C melts more ice than 15 g of liquid water at 100C.arrow_forwardWhite phosphorus, P4, is normally a white, waxy solid melting at 44C to a colorless liquid. The liquid has a vapor pressure of 400.0 mmHg at 251.0C and 760.0 mmHg at 280.0C. What is the heat of vaporization of this substance?arrow_forwardThe vapor pressure of ethanol, C2H5OH, at 50.0 C is 233 mmHg, and its normal boiling point at 1 atm is 78.3 C. Calculate the vapH of ethanol.arrow_forward
- Sketch a phase diagram for O2 from the following information: normal boiling point, 90.18 K; normal melting point, 54.8 K; and triple point, 54.34 K at a pressure of 2 mm Hg. Very roughly estimate the vapor pressure of liquid O2 at 196 C, the lowest temperature easily reached in the laboratory. Is the density of liquid O2 greater or less than that of solid O2?arrow_forwardArrange the following substances in order of increasing strength of crystal forces: CO2, KCl, H2O, N2, CaO.arrow_forwardAn amorphous solid can sometimes be converted to a crystalline solid by a process called annealing. Annealing consists of heating the substance to a temperature just below the melting point of the crystalline form and then cooling it slowly. Explain why this process helps produce a crystalline solid.arrow_forward
- Silicon carbide, SiC, is a very hard, high-melting solid. What kind of crystal forces account for these properties?arrow_forwardAnswer the following questions using Figure 11.12: (a) What is the approximate equilibrium vapor pressure of water at 60 C? Compare your answer with the data in Appendix G. (b) At what temperature does water have an equilibrium vapor pressure of 600 mm Hg? (c) Compare the equilibrium vapor pressures of water and ethanol at 70 C. Which is higher? Figure 11.12 Vapor pressure curves for diethyl ether [(C2H3)2O], ethanol (C2H5OH), and water. Each curve represents conditions of T and P of which the two phases, liquid and vapor, are in equilibrium. These compounds exist as liquids for temperatures and pressures to the left of the curve and as gases under conditions to the right of the curve. (See Appendix G for vapor pressures for water of various temperatures.)arrow_forwardPhase diagrams for materials that have allotropes can be more complicated than those shown in the chapter. Use the phase diagram for carbon given here to answer the following questions. (a) How many triple points are present and what phases are in equilibrium for each? (b) Is there a single point where all four phases are in equilibrium? (c) Which is more stable at high pressures, diamond or graphite? (d) Which is the stable phase of carbon at room temperature and 1 atmosphere pressure?arrow_forward
- Classify each substance in the table as either a metallic, ionic, molecular, or covalent network solid: Substance Appearance Melting Point Electrical Conductivity Solubility in Water X lustrous, malleable 1500 C high insoluble Y Soft, yellow 113 C None Insoluble Z Hard, white 800 C Only if melted/dissolved solublearrow_forwardClassify each substance in the table as either a metallic, ionic, molecular, or covalent network solid: Substance Appearance Melting Point Electrical Conductivity Solubility in Water X brittle, white 800 C only if melted/dissolved soluble Y shiny, malleable 1100 C high insoluble X hard, colorless 3550 C none insolublearrow_forwardTrichloroethane, C2H3Cl3 is used as a degreaser (solvent for waxes and oils). Its density is 1.435 g/mL and its vapor pressure at 20C is 124 mm Hg. (a) How many mL will vaporize in an evacuated 1.50-L flask at 20C? (b) A 3.00-mL sample is poured into an evacuated 1.5-L flask at 20C. Will all the liquid vaporize? If not, what is the pressure in the flask? (c) A similar 3.00-mL sample is poured into an evacuated 20.00-L flask at 20C. What physical state(s) is/are in the flask?arrow_forward
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