PRINCIPLES+REACTIONS
8th Edition
ISBN: 9781337759632
Author: Masterton
Publisher: CENGAGE L
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Question
Chapter 9, Problem 2QAP
(a)
Interpretation Introduction
Interpretation:
The pressure of the vapors of benzene is to be calculated under the given conditions.
Concept Introduction :
The ideal gas equation is the expression that relates different measurable properties of a gas. The expression is given as:
where,
P = Pressure of the gas
V = Volume of the container in which the gas is occupied
R = Ideal gas constant = 0.0821 L atm/ mol K
n = number of moles of the gas = Mass of gas / Molecular mass of gas
T = Absolute temperature of the gas i.e., temperature on Kelvin scale
(b)
Interpretation Introduction
Interpretation:
The pressure calculated in part (a) are to be compared with the equilibrium pressures of benzene.
Concept Introduction :
If the pressure of vapors is more than the equilibrium pressure, it indicates that the liquid has undergone condensation.
(c)
Interpretation Introduction
Interpretation:
The pressure of benzene vapors inside the flask is to be calculated at 50 0C and 60 0C.
Concept Introduction : When a liquid is present in a closed container, it starts to form vapors above the liquid surface. A stage is reached when the liquid and vapors are present in equilibrium with each other.
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For this question, if the product is racemic, input both enantiomers in the same Marvin editor.
A) Input the number that corresponds to the reagent which when added to (E)-but-2-ene will result in a
racemic product.
Input 1 for Cl, in the cold and dark
Input 2 for Oy followed by H₂O, Zn
Input 3 for D₂ with metal catalyst
Input 4 for H₂ with metal catalyst
B) Draw the skeletal structure of the major organic product made from the reagent in part A
Marvin JS
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Edit drawing
C) Draw the skeletal structure of the major organic product formed when (2)-but-2-ene is treated with
peroxyacetic acid.
Marvin 35
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Michael Reactions
19.52 Draw the products from the following Michael addition reactions.
1.
H&C CH
(a)
i
2. H₂O*
(b)
OEt
(c)
EtO
H₂NEt
(d)
ΕΙΟ
+
1. NaOEt
2. H₂O'
H
H
1. NaOEt
2. H₂O*
Chapter 9 Solutions
PRINCIPLES+REACTIONS
Ch. 9 - Prob. 1QAPCh. 9 - Prob. 2QAPCh. 9 - The vapor pressure of I2(s) at 30C is 0.466 mm Hg....Ch. 9 - Prob. 4QAPCh. 9 - Trichloroethane, C2H3Cl3 is used as a degreaser...Ch. 9 - p-Dichlorobenzene, C6H4Cl2, can be one of the...Ch. 9 - Prob. 7QAPCh. 9 - Dichloromethane, CH2Cl2,is widely used as a...Ch. 9 - Prob. 9QAPCh. 9 - Prob. 10QAP
Ch. 9 - At a resort in Sante Fe, New Mexico, the...Ch. 9 - Prob. 12QAPCh. 9 - Prob. 13QAPCh. 9 - Consider the following data for the vapor pressure...Ch. 9 - Referring to Figure 9.7, state what phase(s)...Ch. 9 - Referring to Figure 9.7, state what phase(s) is...Ch. 9 - Prob. 17QAPCh. 9 - Consider the phase diagram of the compound in...Ch. 9 - Prob. 19QAPCh. 9 - Prob. 20QAPCh. 9 - Given the following data about xenon,...Ch. 9 - Given the following data about CO2: • triple...Ch. 9 - A pure substance X has the following properties:...Ch. 9 - Prob. 24QAPCh. 9 - Prob. 25QAPCh. 9 - Arrange the following compounds in order of...Ch. 9 - Which of the following would you expect to show...Ch. 9 - Which of the following compounds would you expect...Ch. 9 - Prob. 29QAPCh. 9 - Prob. 30QAPCh. 9 - Explain in terms of forces between structural...Ch. 9 - Prob. 32QAPCh. 9 - Prob. 33QAPCh. 9 - In which of the following processes is it...Ch. 9 - For each of the following pairs, choose the member...Ch. 9 - Follow the directions for Question 35 for the...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - Prob. 39QAPCh. 9 - Prob. 40QAPCh. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Prob. 43QAPCh. 9 - Prob. 44QAPCh. 9 - Give the formula of a solid containing Si that is...Ch. 9 - Prob. 46QAPCh. 9 - Prob. 47QAPCh. 9 - Describe the structural units in (a) C (graphite)...Ch. 9 - Molybdenum has an atomic radius of 0.145 nm. The...Ch. 9 - Nickel has an atomic radius of 0.162 nm. The edge...Ch. 9 - Lead (atomicradius=0.181nm) crystallizes with a...Ch. 9 - Iridium crystallizes in a face-centered unit cell....Ch. 9 - In the LiCl structure shown in Figure 9.21, the...Ch. 9 - Potassium iodide has a unit cell similar to that...Ch. 9 - Prob. 55QAPCh. 9 - Consider the CsCl cell (Figure 9.21). The ionic...Ch. 9 - Consider the sodium chloride unit cell shown in...Ch. 9 - Consider the CsCl unit shown in Figure 9.21. How...Ch. 9 - A 1.25-L clean and dry flask is sealed. The air in...Ch. 9 - Aluminum metal crystallizes with a face-centered...Ch. 9 - Consider a sealed flask with a movable piston that...Ch. 9 - Prob. 62QAPCh. 9 - Prob. 63QAPCh. 9 - Prob. 64QAPCh. 9 - Chloroform, CHCl3, has a normal boiling point of...Ch. 9 - Prob. 66QAPCh. 9 - Prob. 67QAPCh. 9 - In the blanks provided, answer the questions...Ch. 9 - Answer the questions below, by filling in the...Ch. 9 - Prob. 70QAPCh. 9 - Prob. 71QAPCh. 9 - What is the difference between (a) a covalent bond...Ch. 9 - Four shiny solids are labeled A, B, C, and D....Ch. 9 - Prob. 74QAPCh. 9 - The following data are given for CC14:...Ch. 9 - Iron crystallizes in a body-centered unit cell....Ch. 9 - Prob. 77QAPCh. 9 - Trichloroethane, C2H3Cl3, is the active ingredient...Ch. 9 - Prob. 79QAPCh. 9 - Prob. 80QAPCh. 9 - Prob. 81QAP
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- Rank the labeled protons (Ha-Hd) in order of increasing acidity, starting with the least acidic. НОН НЬ OHd Онсarrow_forwardCan the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left? ? starting material target If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area. Be sure you follow the standard ALEKS rules for submitting syntheses. + More... Note for advanced students: you may assume that you are using a large excess of benzene as your starting material. C :0 T Add/Remove step Garrow_forwardThe following equations represent the formation of compound MX. What is the AH for the electron affinity of X (g)? X₂ (g) → 2X (g) M (s) → M (g) M (g) M (g) + e- AH = 60 kJ/mol AH = 22 kJ/mol X (g) + e-X (g) M* (g) +X (g) → MX (s) AH = 118 kJ/mol AH = ? AH = -190 kJ/mol AH = -100 kJ/mol a) -80 kJ b) -30 kJ c) -20 kJ d) 20 kJ e) 156 kJarrow_forward
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