Zinc metal reacts with hydrochloric acid according to the balanced equation: Zn ( s ) + 2 HCl ( aq ) → ZnCl 2 ( aq ) +H 2 ( g ) When 0.103 g of Zn(s) is combined with enough HCI to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find Δ H rxn for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g °C as the specific heat capacity.)
Zinc metal reacts with hydrochloric acid according to the balanced equation: Zn ( s ) + 2 HCl ( aq ) → ZnCl 2 ( aq ) +H 2 ( g ) When 0.103 g of Zn(s) is combined with enough HCI to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find Δ H rxn for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g °C as the specific heat capacity.)
Solution Summary: The author calculates the enthalpy change of a reaction by applying the law of conservation of energy.
Zinc metal reacts with hydrochloric acid according to the balanced equation:
Zn
(
s
)
+ 2 HCl
(
aq
)
→
ZnCl
2
(
aq
)
+H
2
(
g
)
When 0.103 g of Zn(s) is combined with enough HCI to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find
Δ
H
rxn
for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g °C as the specific heat capacity.)
(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
.
3°C
with
TH
12. (10pts total) Provide the major product for each reaction depicted below. If no reaction
occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction.
3H
24 total (30)
24
21
2h
• 6H total
● 8H total
34
래
Br2
hv
major product
will be most
Substituted
12
hv
Br
NR
I too weak of a
participate in P-1
F₂
hv
Statistically
most favored
product will be
major
=
most subst =
thermo favored
hydrogen atom abstractor to
LL
F
Five chemistry project topic that does not involve practical
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