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Principles of Chemistry: A Molecular Approach Plus Mastering Chemistry with eText -- Access Card Package (3rd Edition) (New Chemistry Titles from Niva Tro)
3rd Edition
ISBN: 9780321971166
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 64E
Calculate
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
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F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
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NH2
Br
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OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
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F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 9 Solutions
Principles of Chemistry: A Molecular Approach Plus Mastering Chemistry with eText -- Access Card Package (3rd Edition) (New Chemistry Titles from Niva Tro)
Ch. 9 - Prob. 9.1PCh. 9 - Arrange the compounds in order or increasing...Ch. 9 - Prob. 9.2MPCh. 9 - Prob. 9.3PCh. 9 - Prob. 9.4PCh. 9 - Prob. 9.5PCh. 9 - Prob. 9.6PCh. 9 - Prob. 9.7PCh. 9 - Prob. 9.8PCh. 9 - Prob. 9.8MP
Ch. 9 - Prob. 9.9PCh. 9 - Write the Lewis structure for XeF4.Ch. 9 - Prob. 9.10MPCh. 9 - Prob. 9.11PCh. 9 - Prob. 9.11MPCh. 9 - Prob. 1SAQCh. 9 - Prob. 2SAQCh. 9 - Prob. 3SAQCh. 9 - Prob. 4SAQCh. 9 - Prob. 5SAQCh. 9 - Prob. 6SAQCh. 9 - Prob. 7SAQCh. 9 - Prob. 8SAQCh. 9 - Prob. 9SAQCh. 9 - Prob. 10SAQCh. 9 - Prob. 11SAQCh. 9 - Prob. 12SAQCh. 9 - Use formal charge to choose the best Lewis...Ch. 9 - Use bond energies to determine Hrxnfor this...Ch. 9 - Prob. 15SAQCh. 9 - Prob. 1ECh. 9 - Prob. 2ECh. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Prob. 5ECh. 9 - Prob. 6ECh. 9 - Prob. 7ECh. 9 - Prob. 8ECh. 9 - Explain the trend in the lattice energies of the...Ch. 9 - Prob. 10ECh. 9 - The lattice enerqy of CsF is -744 kJ/mol, whereas...Ch. 9 - Prob. 12ECh. 9 - Prob. 13ECh. 9 - Prob. 14ECh. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Prob. 18ECh. 9 - Draw the Lewis structure for CO with an arrow...Ch. 9 - Prob. 20ECh. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - Prob. 23ECh. 9 -
24. Write the Lewis structure that obeys the...Ch. 9 - Prob. 25ECh. 9 - Use formal charge to determine which of the two...Ch. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - Prob. 30ECh. 9 - Prob. 31ECh. 9 - What are the formal charges of the atoms shown in...Ch. 9 - Write the Lewis structure for each molecule. a....Ch. 9 - Prob. 34ECh. 9 - Prob. 35ECh. 9 - Prob. 36ECh. 9 - Prob. 37ECh. 9 - Prob. 38ECh. 9 - Consider these three compounds: HCCH, H2CCH2...Ch. 9 - Prob. 40ECh. 9 - Prob. 41ECh. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Prob. 44ECh. 9 - Prob. 45ECh. 9 - Prob. 46ECh. 9 - Prob. 47ECh. 9 - Amino acids are the building blocks of proteins....Ch. 9 - Prob. 49ECh. 9 - Prob. 50ECh. 9 - Prob. 51ECh. 9 - Prob. 52ECh. 9 - Prob. 53ECh. 9 - Prob. 54ECh. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - Prob. 58ECh. 9 - Prob. 59ECh. 9 - Prob. 60ECh. 9 - Prob. 61ECh. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Calculate Hrxn for the combustion of octane...Ch. 9 - 65. Draw the Lewis structure for each compound.
a....Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - Prob. 70ECh. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Prob. 73ECh. 9 - Prob. 74ECh. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Prob. 77ECh. 9 - Prob. 78ECh. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 81ECh. 9 - Prob. 82ECh. 9 - Prob. 83E
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- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
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