Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 9, Problem 5CTQ
Interpretation Introduction

Interpretation: The given mechanism needs to be completed by adding two curved arrows.

  Organic Chemistry: A Guided Inquiry, Chapter 9, Problem 5CTQ

Concept introduction: When the bromine molecule reacts with the C-C double bond, the addition of 2 Br to the double bond takes place. There is the possibility of the formation of both cis and trans products. In the cis product, both bromine atoms are at a cis position to each other and in the trans product, both bromine atoms are at a trans position to each other.

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for the Cl2 addition reaction with 1,2dimethylcyclohexene, draw the most reasonable curved arrow mecanism. based on the reaction products, explain why a carbocation intermediate cannot be proposed
A student adds NBS to a solution of 1-methylcyclohexene and irradiates the mixture with a sunlamp until all the NBS has reacted. After a careful distillation, the product mixture contains two major products of formula C7H11Br. (a) Draw the resonance forms of the three possible allylic free radical intermediates.
2) Provide a detailed mechanism for the addition reaction shown below. State the regiochemistry and explain why it's unusual. Please be sure to include all structures (use line angle notation or perspective diagrams as appropriate to illustrate the stereochemistry of the process), resonance forms, intermkediates, transition states, curved arrows, formal charges, or lone pairs as necessary. Please don't cheat. Br HBr SCH3 SCH + EN
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Organic Chemistry: A Guided Inquiry
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ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning