Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 9, Problem 3CTQ
Interpretation Introduction
Interpretation: The mechanism for the given reaction needs to be shown.
Concept Introduction: Halohydrin is formed when an
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A solution contains 10-3 M (NH4)2CO3 plus 10-3 M CaCO3. (NH4+: pKa 9.26)
a) Follow the four steps and list the species and equations that would have to be solved
to determine the equilibrium solution composition. (15 pts)
b) Prepare a log C-pH diagram for the solution. Use a full sheet of graph paper, and
show the ranges 1≤ pH < 13 and -10≤ log C≤ -1. (10 pts)
c) Use the graphical approach for the solution pH. What is the concentration of all
species? (15 pts)
Keggin structure.
Given: N2(g) + 3H2(g)2NH3(g)
AG° = 53.8 kJ at 700K. Calculate AG for the above reaction at 700K if the reaction mixture consists of 20.0 atm of N2(g),
30.0 atm of H2(g), and 0.500 atm of NH3(g).
A) -26.9 kJ
B) 31.1 kJ
C) -15.6 kJ
D) 26.9 kJ
E) -25.5 kJ
Chapter 9 Solutions
Organic Chemistry: A Guided Inquiry
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