Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Textbook Question
Chapter 9, Problem 53E
Provide the formula for each acid
- hydrofluoric acid
- hydrobromic acid
- sulfurous acid
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 9 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 9 - Prob. 1SAQCh. 9 - What mass (in grams) of Mg(NO3)2 is present in 145...Ch. 9 - Prob. 3SAQCh. 9 - Potassium iodide reacts with lead(ll) nitrate in...Ch. 9 - Which solution forms a precipitate when mixed with...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the oxidation state of carbon in CO32-? +3...Ch. 9 - Prob. 10SAQ
Ch. 9 - Prob. 11SAQCh. 9 - What is an aqueous solution? What is the...Ch. 9 - What is molarity? How is it useful?Ch. 9 - Explain how a strong electrolyte, a weak...Ch. 9 - What is an acid? Explain the difference between a...Ch. 9 - What does it mean for a compound to be soluble?...Ch. 9 - What are the solubility rules? How are they...Ch. 9 - Which cations and anions form compounds that are...Ch. 9 - What is a precipitation reaction? Give an example.Ch. 9 - How can you predict whether a precipitation...Ch. 9 - Explain how a molecular equation, a complete ionic...Ch. 9 - Prob. 11ECh. 9 - Prob. 12ECh. 9 - Prob. 13ECh. 9 - Explain the principles behind an acid-base...Ch. 9 - Prob. 15ECh. 9 - Which reactant types give rise to gas-evolution...Ch. 9 - Prob. 17ECh. 9 - What are oxidation states? How can oxidation...Ch. 9 - What happens to a substance when it becomes...Ch. 9 - In a redox reaction, which reactant is the...Ch. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - What is the molarity of NO3- in each solution?...Ch. 9 - What is the molarity of Cl- in each solution?...Ch. 9 - Prob. 25ECh. 9 - Prob. 26ECh. 9 - A laboratory procedure calls for making 400.0 mL...Ch. 9 - Prob. 28ECh. 9 - If 123 mL of a 1.1 M glucose solution is diluted...Ch. 9 - If 3.5 L of a 4.8 M SrCl2 solution is diluted to...Ch. 9 - To what volume should you dilute 50.0 mL of a 12 M...Ch. 9 - Prob. 32ECh. 9 - Consider the precipitation reaction:...Ch. 9 - Consider the reaction:...Ch. 9 - What is the minimum amount of 6.0 M H2SO4...Ch. 9 - What molarity of ZnCl2forms when 25.0 g of zinc...Ch. 9 - You mix a 25.0 mL sample of a 1.20 M potassium...Ch. 9 - Prob. 38ECh. 9 - For each compound (all water soluble), would you...Ch. 9 - Classify each compound as a strong electrolyte or...Ch. 9 - Determine whether each compound is soluble or...Ch. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Complete and balance each equation. If no reaction...Ch. 9 - Write a molecular equation for the precipitation...Ch. 9 - Write a molecular equation for the precipitation...Ch. 9 - Write balanced complete ionic and net ionic...Ch. 9 - Write balanced complete ionic and net ionic...Ch. 9 - Mercury ions (Hg22+) can be removed from solution...Ch. 9 - Lead ions can be removed from solution by...Ch. 9 - Name each acid. Hl(aq) HNO3(aq) H2CO3(aq)Ch. 9 - Name each acid HCI(aq) HClO2(aq) H2SO4(aq)Ch. 9 - Provide the formula for each acid hydrofluoric...Ch. 9 - Provide the formula for each acid phosphoric acid...Ch. 9 - Write balanced molecular and net ionic equations...Ch. 9 - Write balanced molecular and net ionic equations...Ch. 9 - Complete and balance each acid-base equation...Ch. 9 - Complete and balance each acid-base equation...Ch. 9 - A 25.00-mL sample of an unknown HClO4solution...Ch. 9 - A 30.00-mL sample of an unknown H3PO4 solution is...Ch. 9 - Complete and balance each gas-evolution equation:...Ch. 9 - Prob. 62ECh. 9 - Write a balanced equation for the reaction between...Ch. 9 - Prob. 64ECh. 9 - Assign oxidation states to each atom in each...Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Determine whether or not each reaction is a redox...Ch. 9 - Determine whether or not each reaction is a redox...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - People often use sodium bicarbonate as an antacid...Ch. 9 - Toilet bowl cleaners often contain hydrochloric...Ch. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Predict the products and write a balanced...Ch. 9 - Predict the products and write a balanced...Ch. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 81ECh. 9 - A solution contains Cr3+ ion and Mg2+ ion. The...Ch. 9 - Find the volume of 0.110 M hydrochloric acid...Ch. 9 - Find the volume of 0.150 M sulfuric acid necessary...Ch. 9 - Treatment of gold metal with BrF3 and KF produces...Ch. 9 - We prepare a solution by mixing 0.10 L of 0.12 M...Ch. 9 - A solution contains Ag +and Hg2+ions. The addition...Ch. 9 - The water in lakes that have been acidified by...Ch. 9 - Recall from Section 8.5 that sodium carbonate is...Ch. 9 - A solution contains one or more of the following...Ch. 9 - A solution contains one or more of the following...Ch. 9 - Prob. 92ECh. 9 - Prob. 93ECh. 9 - Prob. 94ECh. 9 - Prob. 95E
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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