Thinking Like an Engineer: An Active Learning Approach (4th Edition)
Thinking Like an Engineer: An Active Learning Approach (4th Edition)
4th Edition
ISBN: 9780134639673
Author: Elizabeth A. Stephan, David R. Bowman, William J. Park, Benjamin L. Sill, Matthew W. Ohland
Publisher: PEARSON
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Chapter 9, Problem 4RQ
  1. 4. The Arrhenius number (Ar) is the dimensionless parameter describing the ratio of activation energy to thermal energy, often used in chemistry. It depends on the following quantities:

Ea = activation energy [=] J/mol

R = ideal gas constant [=] (atm L) / (mol K)

T = temperature [=] K

Use your knowledge of dimensions to determine the proper form of the Arrhenius number, choosing from the options below.

  1. A.    A r = E a R T
  2. B.     Ar = Ea RT
  3. C.     A r = R T 2 E a
  4. D.    A r = E a T R
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physical quantities m, r, u, a, and t with dimensions [m] = M, [r]= L, [v] = LT, [a] = LT-2, and [t] = T. Enter the dimensional expression of the quantity on the right-hand side of each equation. Your answers may contain only M, L, T, and exponents. Assume that each of the following equations is dimensionally consistent. F = ma [F] =
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3. Consider the following equation. All three of the terms in parentheses are dimensionless groups. Because kc is difficult to determine directly, the other variables are measured and kc is calculated from the given equation. 26 THERMODYNAMICS 1 MODULE 1 FUNDAMENTAL CONCEPTS ]3 [ _d>vp_jo8 p DAB kc D = 0.023 [H DAB What is the estimated value of kc? What are the units of kc? Show your work. The following values were measured: D = 8.0 mm, DAB = 0.475 cm²/s, µ = 1.12 x 103 N-s/m², p = 1.00 x 10-³ g/cm³, v = 15.0 m/s.

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