ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 9, Problem 18P

All compounds in Problem 9.17 are isomers except one. Which one?

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Four liters of an aqueous solution containing 6.98 mg of acetic acid were prepared. At 25°C, the measured conductivity was 5.89x10-3 mS cm-1. Calculate the degree of dissociation of the acid and its ionization constant.Molecular weights: O (15.999), C (12.011), H (1.008).Limiting molar ionic conductivities (λ+0 and λ-0) of Ac-(aq) and H+(aq): 40.9 and 349.8 S cm-2 mol-1.
Determine the change in Gibbs energy, entropy, and enthalpy at 25°C for the battery from which the data in the table were obtained.T (°C)          15           20          25         30          35Eo (mV)   227.13   224.38   221.87   219.37   216.59Data: n = 1, F = 96485 C mol–1
Indicate the correct options.1. The units of the transport number are Siemens per mole.2. The Siemens and the ohm are not equivalent.3. The Van't Hoff factor is dimensionless.4. Molar conductivity does not depend on the electrolyte concentration.

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ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<

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