The heat of vaporization of water at the normal boiling point,
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- The cooling effect of alcohol on the skin is due to its evaporation. Calculate the heat of vaporization of ethanol (ethyl alcohol), C2H5OH. C2H5OH(l)C2H5OH(g);H=? The standard enthalpy of formation of C2H5OH(l) is 277.7 kJ/mol and that of C2H5OH(g) is 235.1 kJ/mol.arrow_forwardLiquid butane, C4H10, is stored in cylinders to be used as a fuel. Suppose 35.5 g of butane gas is removed from a cylinder. How much heat must be provided to vaporize this much gas? The heat of vaporization of butane is 21.3 kJ/mol.arrow_forwardCalculate the quantity of heating required to convert the water in four ice cubes (60.1 g each) from H2O(s) at 0 °C to H2O(g) at 100. °C. The enthalpy of fusion of ice is 333 J/g and the enthalpy of vaporization of liquid water is 2260 J/g.arrow_forward
- Are changes in state physical or chemical changes? Explain. What type of forces must be overcome to melt or vaporize a substance (are these forces intramolecular or intermolecular)? Define the molar heat of fusion and molar heat of vaporization. Why is the molar heat of vaporization of water so much larger than its molar heat of fusion? Why does the boiling point of a liquid vary with altitude?arrow_forwardExplain why the enthalpies of vaporization of the following substances increase in the order CH4NH3H2O, even though all three substances have approximately the same molar mass.arrow_forwardA 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0C. The reaction is 2Na(s)+2H2O(l)2NaOH(aq)+H2(g)H=368kJ Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/gc, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.arrow_forward
- Use Figure 11.7 to estimate the boiling point of carbon tetrachloride, CCl4, under an external pressure of 250 mmHg.arrow_forwardThe vapor pressure of ethanol, C2H5OH, at 50.0 C is 233 mmHg, and its normal boiling point at 1 atm is 78.3 C. Calculate the vapH of ethanol.arrow_forwardA quantity of ice at 0C is added to 64.3 g of water in a glass at 55C. After the ice melted, the temperature of the water in the glass was 15C. How much ice was added? The heat of fusion of water is 6.01 kJ/mol and the specific heat is 4.18 J/(g C).arrow_forward
- Consider the iodine monochloride molecule, ICI. Because chlorine is more electronegative than iodine, this molecule is a dipole. How would you expect iodine monochloride molecules in the gaseous state to orient themselves with respect to each other as the sample is cooled and the molecules begin to aggregate? Sketch the orientation you would expect.arrow_forwardConsider two different organic compounds, each with the formula C2H6O. One of these compounds is a liquid at room conditions and the other is a gas. Write Lewis structures consistent with this observation, and explain your answer. (Hint: The oxygen atom in both structures satisfies the octet rule with two bonds and two lone pairs.)arrow_forwardThe phase diagram for water over a relative narrow pressure and temperature range is given in Figure 9.19. A phase diagram over a considerably wider range of temperature and pressure (kbar) is given nearby. This phase diagram illustrates the polymorphism of ice, the existence of a solid in more than one form. In this case, Roman numerals are used to designate each polymorphic form. For example, Ice I, ordinary ice, is the form that exists under ordinary pressures. The other forms exist only at higher pressures, in some cases extremely high pressure such as Ice VII and Ice VIII. Using the phase diagram, give the approximate P and T conditions at the triple point for Ice III, Ice V, and liquid water. Determine the approximate temperature and pressure for the triple point for Ices VI, VII, and VIII. What is anomalously different about the fusion curves for Ice VI and Ice VII compared to that of Ice I? What phases exist at 8 kbar and 20 °C? At a constant temperature of −10 °C, start at 3 kbar and increase the pressure to 7 kbar. Identify all the phase changes that occur sequentially as these conditions change. Explain why there is no triple point for the combination of Ice VII, Ice VIII, and liquid water.arrow_forward
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