When atoms lose more than one electron, the ionization energy to remove the second electron is always more than the ionization energy to remove the first. Similarly, the ionization energy to remove the third electron is more than the second and so on. However, the increase in ionization energy upon the removal of subsequent electrons is not necessarily uniform. For example, consider the first three ionization energies of magnesium: First ionization energy 738 kJ/mol Second ionization energy 1450 kJ/mol Third ionization energy 7730 kJ/mol The second ionization energy is roughly twice the first ionization energy, but then the third ionization energy is over five times the second. Use the electron configuration of magnesium to explain why this is so. Would you expect the same behaviour in sodium? Why or why not?
When atoms lose more than one electron, the ionization energy to remove the second electron is always more than the ionization energy to remove the first. Similarly, the ionization energy to remove the third electron is more than the second and so on. However, the increase in ionization energy upon the removal of subsequent electrons is not necessarily uniform. For example, consider the first three ionization energies of magnesium: First ionization energy 738 kJ/mol Second ionization energy 1450 kJ/mol Third ionization energy 7730 kJ/mol The second ionization energy is roughly twice the first ionization energy, but then the third ionization energy is over five times the second. Use the electron configuration of magnesium to explain why this is so. Would you expect the same behaviour in sodium? Why or why not?
Solution Summary: The author explains the first, second and third ionization energies of magnesium and sodium.
When atoms lose more than one electron, the ionization energy to remove the second electron is always more than the ionization energy to remove the first. Similarly, the ionization energy to remove the third electron is more than the second and so on. However, the increase in ionization energy upon the removal of subsequent electrons is not necessarily uniform. For example, consider the first three ionization energies of magnesium:
First ionization energy
738 kJ/mol
Second ionization energy
1450 kJ/mol
Third ionization energy
7730 kJ/mol
The second ionization energy is roughly twice the first ionization energy, but then the third ionization energy is over five times the second. Use the electron configuration of magnesium to explain why this is so. Would you expect the same behaviour in sodium? Why or why not?
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