EBK INTRODUCTION TO CHEMISTRY
5th Edition
ISBN: 9781260162165
Author: BAUER
Publisher: MCGRAW HILL BOOK COMPANY
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Chapter 9, Problem 109QP
Interpretation Introduction
Interpretation:
The arrangement of the given gases in the increasing order of average velocity of gases is to be determined.
Concept Introduction:
The kinetic energy of a gas is given by the equation shown below:
At constant temperature, the kinetic energy of the different gases is the same. The average velocity of a gas particle depends upon the kinetic energy of the gas.
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and
gives compound A.
?
NH2
Br
Br
Propose a structural formula for compound A.
You do not have to explicitly draw H atoms.
You do not have to consider stereochemistry.
In cases where there is more than one answer, just draw one.
R3N
C14H19NO2
+ 2 R3NH*Br
A
Chapter 9 Solutions
EBK INTRODUCTION TO CHEMISTRY
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