Major and minor product should be predicted for the given alkyl halide during E1 elimination process. Concept introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2. E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation. E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state. Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat. Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 1

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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personality of each of them in terms of nucleophile vs. electrophile (some can be considered acids/bases but we are not looking at that here). Note you may have to use your growing intuition to figure out the personality of one of the molecules below but I believe in you! Rationalize it out based on what we have called strong versus weak electrophiles in past mechanisms. Consider using the memes below to help guide your understanding! A OH O B CH3 C Molecule A: [Select] Molecule B: [Select] Molecule C: [Select] Molecule D: [Select] > H D OH

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Answer 2

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 3

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 4

Question

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

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Answer 5

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 6

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 7

Chapter 8.9, Problem 29PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be predicted for the given alkyl halide during E1 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. In this process, intermediate is carbocation.

E2 reaction: elimination follows concerted pathway of mechanism. In this process, there is intermediate only transition state.

Dehydration: elimination of water molecule from the substrate is known as dehydration process. This reaction leads in presence of concentrated sulfuric acid followed by heat.

Dehydro halogenation: elimination of hydrogen halide from the substrate is known as dehydro halogenation process. This reaction leads in acidic media.

Answer 14

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Answer 17

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

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