Introductory Chemistry >IC<
8th Edition
ISBN: 9781305014534
Author: ZUMDAHL
Publisher: CENGAGE C
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Chapter 8.8, Problem 8.9SC
trong>Exercise 8.9 Sevin, the commercial name for an insecticide used to protect crops such as cotton, vegetables, and fruit, is made from carbamic acid. A chemist analyzing a sample of carbamic acid finds 0.8007 g of carbon, 0.9333 g of nitrogen, 0.2016 g of hydrogen, and 2.133 g of oxygen. Determine the empirical formula for carbamic acid.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 8 Solutions
Introductory Chemistry >IC<
Ch. 8.2 - ercise 8.1 Calculate the mass of a sample that...Ch. 8.2 - Prob. 8.2SCCh. 8.3 - at if you were offered $1 million to count from 1...Ch. 8.3 - at if you discovered Avogadro’s number was not...Ch. 8.3 - ercise 8.3 Chromium (Cr) is a metal that is added...Ch. 8.5 - ercise 8.4 Polyvinyl chloride (called PVC), which...Ch. 8.5 - ercise 8.5 Calculate the molar mass for sodium...Ch. 8.5 - ercise 8.6 The substance Teflon, the slippery...Ch. 8.6 - ercise 8.7 Penicillin, an important antibiotic...Ch. 8.8 - ercise 8.8 In a lab experiment it was observed...
Ch. 8.8 - trong>Exercise 8.9 Sevin, the commercial name for...Ch. 8.8 - e part of the problem-solving strategy for...Ch. 8.8 - ercise 8.10 The most common form of nylon...Ch. 8.9 - Exercise 8.11 A compound used as an additive for...Ch. 8 - n chemistry, what is meant by the term mole? What...Ch. 8 - hat is the difference between the empirical and...Ch. 8 - substance A2B is 60% A by mass. Calculate the...Ch. 8 - ive the formula for calcium phosphate and then...Ch. 8 - ow would you find the number of “chalk molecules”...Ch. 8 - 0.821 -mol sample of a substance composed of...Ch. 8 - ow many molecules of water are there in a 10.0-g...Ch. 8 - hat is the mass (in grams) of one molecule of...Ch. 8 - onsider separate 100.0-g samples of each of the...Ch. 8 - A molecule has a mass of 4.651023 g. Provide two...Ch. 8 - Differentiate between the terms atomic mass and...Ch. 8 - Consider Figure 4.19 in the text. Why is it that...Ch. 8 - Why do we need to count atoms by weighing them?Ch. 8 - The following claim is made in your text: 1 mole...Ch. 8 - Estimate the length of time it would take you to...Ch. 8 - Suppose Avogadro’s number was 1000 instead of...Ch. 8 - Estimate the number of atoms in your body and...Ch. 8 - Consider separate equal mass samples of magnesium,...Ch. 8 - You have a 20.0-g sample of silver metal. You are...Ch. 8 - How would you find the number of “ink molecules”...Ch. 8 - True or false? The atom with the largest subscript...Ch. 8 - Which of the following compounds have the same...Ch. 8 - The percent by mass of nitrogen is 46.7% for a...Ch. 8 - Prob. 24ALQCh. 8 - Give the empirical formula for each of the...Ch. 8 - erchants usually sell small nuts, washers, and...Ch. 8 - he “Chemistry in Focus” segment Plastic That Talks...Ch. 8 - efine the amu. 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