
Introductory Chemistry >IC<
8th Edition
ISBN: 9781305014534
Author: ZUMDAHL
Publisher: CENGAGE C
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Textbook Question
Chapter 8, Problem 22ALQ
Which of the following compounds have the same empirical formulas?
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 8 Solutions
Introductory Chemistry >IC<
Ch. 8.2 - ercise 8.1 Calculate the mass of a sample that...Ch. 8.2 - Prob. 8.2SCCh. 8.3 - at if you were offered $1 million to count from 1...Ch. 8.3 - at if you discovered Avogadro’s number was not...Ch. 8.3 - ercise 8.3 Chromium (Cr) is a metal that is added...Ch. 8.5 - ercise 8.4 Polyvinyl chloride (called PVC), which...Ch. 8.5 - ercise 8.5 Calculate the molar mass for sodium...Ch. 8.5 - ercise 8.6 The substance Teflon, the slippery...Ch. 8.6 - ercise 8.7 Penicillin, an important antibiotic...Ch. 8.8 - ercise 8.8 In a lab experiment it was observed...
Ch. 8.8 - trong>Exercise 8.9 Sevin, the commercial name for...Ch. 8.8 - e part of the problem-solving strategy for...Ch. 8.8 - ercise 8.10 The most common form of nylon...Ch. 8.9 - Exercise 8.11 A compound used as an additive for...Ch. 8 - n chemistry, what is meant by the term mole? What...Ch. 8 - hat is the difference between the empirical and...Ch. 8 - substance A2B is 60% A by mass. Calculate the...Ch. 8 - ive the formula for calcium phosphate and then...Ch. 8 - ow would you find the number of “chalk molecules”...Ch. 8 - 0.821 -mol sample of a substance composed of...Ch. 8 - ow many molecules of water are there in a 10.0-g...Ch. 8 - hat is the mass (in grams) of one molecule of...Ch. 8 - onsider separate 100.0-g samples of each of the...Ch. 8 - A molecule has a mass of 4.651023 g. Provide two...Ch. 8 - Differentiate between the terms atomic mass and...Ch. 8 - Consider Figure 4.19 in the text. Why is it that...Ch. 8 - Why do we need to count atoms by weighing them?Ch. 8 - The following claim is made in your text: 1 mole...Ch. 8 - Estimate the length of time it would take you to...Ch. 8 - Suppose Avogadro’s number was 1000 instead of...Ch. 8 - Estimate the number of atoms in your body and...Ch. 8 - Consider separate equal mass samples of magnesium,...Ch. 8 - You have a 20.0-g sample of silver metal. You are...Ch. 8 - How would you find the number of “ink molecules”...Ch. 8 - True or false? The atom with the largest subscript...Ch. 8 - Which of the following compounds have the same...Ch. 8 - The percent by mass of nitrogen is 46.7% for a...Ch. 8 - Prob. 24ALQCh. 8 - Give the empirical formula for each of the...Ch. 8 - erchants usually sell small nuts, washers, and...Ch. 8 - he “Chemistry in Focus” segment Plastic That Talks...Ch. 8 - efine the amu. What is one amu equivalent to in...Ch. 8 - hat do we mean by the average atomic mass of an...Ch. 8 - sing the average atomic masses for each of the...Ch. 8 - sing the average atomic masses for each of the...Ch. 8 - Prob. 7QAPCh. 8 - The atomic mass of bromine is 79.90 amu. What...Ch. 8 - here are _________ iron atoms present in 55.85 g...Ch. 8 - There are 6.0221023 zinc atoms present in g of...Ch. 8 - Suppose you have a sample of sodium weighing 11.50...Ch. 8 - Consider a sample of silver weighing 30OE0 g. How...Ch. 8 - What mass of hydrogen contains the same number of...Ch. 8 - What mass of cobalt contains the same number of...Ch. 8 - If an average sodium atom has a mass of 3.821023...Ch. 8 - Ifan average fluorine atom has a mass of 3.161023...Ch. 8 - Which has the smaller mass, 1 mole of He atoms or...Ch. 8 - Which weighs less, 0.25 mole of xenon atoms or 2.0...Ch. 8 - Use the average atomic masses given inside the...Ch. 8 - Use the average atomic masses given inside the...Ch. 8 - Use the average atomic masses given inside the...Ch. 8 - Use the average atomic masses given inside the...Ch. 8 - Using the average atomic masses given inside the...Ch. 8 - Using the average atomic masses given inside the...Ch. 8 - The _________ of a substance is the mass (in...Ch. 8 - Prob. 26QAPCh. 8 - Give the name and calculate the molar mass for...Ch. 8 - Give the name and calculate the molar mass for...Ch. 8 - Write the formula and calculate the molar mass for...Ch. 8 - Prob. 30QAPCh. 8 - Calculate the number of moles of the indicated...Ch. 8 - Prob. 32QAPCh. 8 - Prob. 33QAPCh. 8 - Calculate the number of moles of the indicated...Ch. 8 - Calculate the mass in grams of each of the...Ch. 8 - Calculate the mass in grams of each of the...Ch. 8 - Calculate the mass in grams of each of the...Ch. 8 - Calculate the mass in grams of each of the...Ch. 8 - Calculate the number of molecules present in each...Ch. 8 - Calculate the number of molecules present in each...Ch. 8 - Calculate the number of moles of carbon atoms...Ch. 8 - Calculate the number of moles of sulfur atoms...Ch. 8 - The mass fraction of an element present in a...Ch. 8 - If the amount of a sample doubles, what happens to...Ch. 8 - lculate the percent by mass of each element in the...Ch. 8 - Calculate the percent by mass of each element in...Ch. 8 - Calculate the percent by mass of the element...Ch. 8 - Calculate the percent by mass of the element...Ch. 8 - Prob. 49QAPCh. 8 - What is the mass percent of oxygen in each of the...Ch. 8 - For each of the following samples of ionic...Ch. 8 - For each of the following ionic substances,...Ch. 8 - Prob. 53QAPCh. 8 - Explain lo a friend who has not yet taken a...Ch. 8 - Give the empirical formula that corresponds to...Ch. 8 - Which of the following pairs of compounds have the...Ch. 8 - A compound was analyzed and was found to contain...Ch. 8 - A compound was analyzed and was found to contain...Ch. 8 - A 0.59980-g sample of a new compound has been...Ch. 8 - A compound was analyzed and was found to contain...Ch. 8 - If a 1.271-g sample of aluminum metal is heated in...Ch. 8 - A compound was analyzed and was found to contain...Ch. 8 - When 3.269 g of zinc is heated in pure oxygen, the...Ch. 8 - If cobalt metal is mixed with excess sulfur and...Ch. 8 - If 1.25 g of aluminum metal is heated in an...Ch. 8 - If 2.50 g of aluminum metal is heated in a stream...Ch. 8 - A compound used ¡n the nuclear industry has the...Ch. 8 - A compound was analyzed and was found to contain...Ch. 8 - A compound has the following percentage...Ch. 8 - When lithium metal is heated strongly in an...Ch. 8 - A compound has been analyzed and has been found to...Ch. 8 - Tetraphenylporphyrin is a synthetic compound that...Ch. 8 - When 1.00 mg of lithium metal is reacted with...Ch. 8 - Phosphorus and chlorine form two binary compounds,...Ch. 8 - How does the molecular formula of a compound...Ch. 8 - Prob. 76QAPCh. 8 - A binary compound of boron and hydrogen has the...Ch. 8 - A compound with empirical formula CH was found by...Ch. 8 - A compound with the empirical formula CH2 was...Ch. 8 - A compound with empirical formula C2H5O was found...Ch. 8 - A compound having an approximate molar mass of...Ch. 8 - A compound consists of carbon and hydrogen. The...Ch. 8 - Use the periodic table shown in Fig. 4.9 to...Ch. 8 - Complete the following table. l> Mass of Sample...Ch. 8 - Complete the following table. l> Mass of Sample...Ch. 8 - Consider a hypothetical compound composed of...Ch. 8 - A binary compound of magnesium and nitrogen is...Ch. 8 - When a 2.11 8-g sample of copper is heated in an...Ch. 8 - Hydrogen gas reacts with each of the halogen...Ch. 8 - Calculate the number of atoms of each element...Ch. 8 - Calculate the mass in grams of each of the...Ch. 8 - Calculate the mass of carbon in grams, the percent...Ch. 8 - Find the item in column 2 that best explains or...Ch. 8 - Prob. 94APCh. 8 - Calculate the number of grams of cobalt that...Ch. 8 - Prob. 96APCh. 8 - Calculate the number of grains of lithium that...Ch. 8 - Given that the molar mass of carbon tetrachloride,...Ch. 8 - Calculate the mass in grains of hydrogen present...Ch. 8 - f you have equal mole samples of NO2 and F2 ,...Ch. 8 - strikingly beautiful copper compound with the...Ch. 8 - Prob. 102APCh. 8 - Prob. 103APCh. 8 - Prob. 104APCh. 8 - Prob. 105APCh. 8 - f an average sodium atom weighs 22.99 amu, how...Ch. 8 - Prob. 107APCh. 8 - Prob. 108APCh. 8 - Prob. 109APCh. 8 - Prob. 110APCh. 8 - Prob. 111APCh. 8 - Prob. 112APCh. 8 - alculate the number of moles of the indicated...Ch. 8 - Consider equal mole samples of tetraphosphorus...Ch. 8 - Prob. 115APCh. 8 - Prob. 116APCh. 8 - alculate the number of moles of hydrogen atoms...Ch. 8 - ow many anions are there in 5.00 g of calcium...Ch. 8 - Prob. 119APCh. 8 - Prob. 120APCh. 8 - 1.2569-g sample of a new compound has been...Ch. 8 - hat mass of sodium hydroxide has the same number...Ch. 8 - hen 2.004 g of calcium is heated in pure nitrogen...Ch. 8 - You find a compound composed only of element X and...Ch. 8 - hen 1.00 g of metallic chromium is heated with...Ch. 8 - hen barium metal is heated in chlorine gas, a...Ch. 8 - Prob. 127CPCh. 8 - itamin B12 , cyancobalamin, is essential for human...Ch. 8 - Prob. 129CPCh. 8 - . How many atoms of carbon are present in 1 .0 g...Ch. 8 - onsider samples of phosphine (PH3) , water (H2O) ....Ch. 8 - he chemical formula for aspirin is C9H8O4 . What...Ch. 8 - Prob. 133CPCh. 8 - compound with molar mass 180.1 g/mol has the...
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
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