Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 8.2, Problem 2E
Interpretation Introduction

Interpretation: The reduced mass for the bond C-H needs to be determined the equation 8.4 needs to be used for predicting the value of ν¯CH equals to 3040/cm.

Concept introduction:

There is a large variance in force constant when there are small differences in bond length. It is known that wavenumber is inversely proportional to square root of reduced mass. With an increase in reduced mass, there is a decrease in wavenumber. Reduced mass is considered as the quantity which allows the two-body problem to be solved as one body problem.

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